dc.creator | González Castaño, Míriam | es |
dc.creator | Ivanova, Svetlana | es |
dc.creator | Laguna Espitia, Oscar Hernando | es |
dc.creator | Martínez Tejada, Leidy Marcela | es |
dc.creator | Centeno Gallego, Miguel Ángel | es |
dc.creator | Odriozola Gordón, José Antonio | es |
dc.date.accessioned | 2018-11-16T16:01:55Z | |
dc.date.available | 2018-11-16T16:01:55Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | González Castaño, M., Ivanova, S., Laguna Espitia, O.H., Martínez Tejada, L.M., Centeno Gallego, M.Á. y Odriozola Gordón, J.A. (2017). Structuring Pt/CeO2/Al2O3 WGS catalyst: Introduction of buffer layer. Applied Catalysis B, Environmental, 200, 420-427. | |
dc.identifier.issn | 0926-3373 | es |
dc.identifier.uri | https://hdl.handle.net/11441/80304 | |
dc.description.abstract | This work is devoted to the development of novel structured catalytic system for WGS reaction. The new concept is related to the presence of a pre-catalytic “buffer” layer formed by WGS-inert oxide, i.e. not involved in CO conversion, but able to increase the number of participating sites in water dissociation step during the reaction. The performance of the proposed systems appears to depend strongly on the stream composition, being its effect beneficial in highly reducing atmospheres making it ideal for clean-up application. An increment of the partial kinetic order for water species is observed and reveals the key role of the water activation for superior catalytic behavior. | es |
dc.description.sponsorship | Junta de Andalucía TEP-8196 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Elsevier | es |
dc.relation.ispartof | Applied Catalysis B, Environmental, 200, 420-427. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | WGS | es |
dc.subject | Monoliths | es |
dc.subject | Buffer layer | es |
dc.subject | Platinum catalysts | es |
dc.subject | Structured catalyst | es |
dc.title | Structuring Pt/CeO2/Al2O3 WGS catalyst: Introduction of buffer layer | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.projectID | TEP-8196 | es |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.apcatb.2016.07.039 | es |
dc.identifier.doi | 10.1016/j.apcatb.2016.07.039 | es |
idus.format.extent | 40 p. | es |
dc.journaltitle | Applied Catalysis B, Environmental | es |
dc.publication.volumen | 200 | es |
dc.publication.initialPage | 420 | es |
dc.publication.endPage | 427 | es |
dc.contributor.funder | Junta de Andalucía | |