High and stable Co2 capture capacity of natural limestone at Ca-looping conditions by heat pretreatment and recarbonation synergy

Abstract

The Ca-looping (CaL) process, based on the multicyclic carbonation/ calcination of limestone derived CaO, has emerged recently as a potentially economically advantageous technology to achieve sustainable postcombustion and precombustion CO2 capture efficiencies. Yet, a drawback that hinders the efficiency of the CaL process is the drastic drop of limestone capture capacity as the number of carbonation/calcination cycles is increased. Precalcination of limestone at high temperatures for a prolonged period of time has been proposed as a potential technique to reactivate the sorbent, which is however precluded by regeneration temperatures above 850 C and low CO2 concentrations in the carbonator to be found in the practical situation. Under these conditions, heat pretreatment leads to a stable yet very small CaO conversion. On the other hand, the introduction of a recarbonation stage between the ordinary carbonation and calcination stages has been shown to decelerate the rate of sorbent activity decay even though this favorable effect is not noticeable up to a number of above 10-15 cycles. The present manuscript demonstrates that the synergetic action of heat pretreatment and recarbonation yields a high and stable value for the multicyclic conversion of limestone derived CaO. It is foreseen that recarbonation of heat pretreated limestone would lead to a reduction of process costs especially in the case of precombustion applications. Even though sorbent purging will always be needed because of ash accumulation and sulphation in postcombustion CO2 capture applications, the stable and high multicyclic CaO conversion achieved by the combination of these techniques would make it necessary to a lesser extent.