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Dependence of the preexponential factor on temperature

 

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Opened Access Dependence of the preexponential factor on temperature
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Author: Criado Luque, José Manuel
Pérez Maqueda, Luis Allan
Sánchez Jiménez, Pedro Enrique
Department: Universidad de Sevilla. Departamento de Química Inorgánica
Date: 2005
Published in: Journal of Thermal Analysis and Callorimetry, 82 (3), 1-14.
Document type: Article
Abstract: The dependence of the preexponential factor on the temperature has been examined and the errors involved in the activation energy calculated from isothermal and non-isothermal methods without considering such dependence have been estimated. It has been shown that the error in the determination of the activation energy calculated ignoring the dependence of Aon Tcan be rather large and it is dependent on x=E/RT, but independent of the experimental method used. It has been also shown that the error introduced by omitting the dependence of the preexponential factor on the temperature is considerably larger than the error due to the Arrhenius integral approach used for carrying out the kinetic analysis of TG data.
Cite: Criado Luque, J.M., Pérez Maqueda, L.A. y Sánchez Jiménez, P.E. (2005). Dependence of the preexponential factor on temperature. Journal of Thermal Analysis and Callorimetry, 82 (3), 1-14.
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URI: https://hdl.handle.net/11441/74154

DOI: 10.1007/s10973-005-0948-3

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