dc.creator | Sánchez Jiménez, Pedro Enrique | es |
dc.creator | Criado Luque, José Manuel | es |
dc.creator | Pérez Maqueda, Luis Allan | es |
dc.date.accessioned | 2018-02-20T17:08:14Z | |
dc.date.available | 2018-02-20T17:08:14Z | |
dc.date.issued | 2008 | |
dc.identifier.citation | Sánchez Jiménez, P.E., Criado Luque, J.M. y Pérez Maqueda, L.A. (2008). Kissinger kinetic analysis of data obtained under different heating schedules. Journal of Thermal Analysis and Calorimetry, 94 (2), 427-432. | |
dc.identifier.issn | 1388-6150 (impreso) | es |
dc.identifier.issn | 1588-2926 (electrónico) | es |
dc.identifier.uri | https://hdl.handle.net/11441/70456 | |
dc.description.abstract | The dynamic heating rate method developed by TA Instruments (
Hi-Res
™
) is a kind of sample
controlled thermal analysis in which a linear relati
onship between the logarith
m of the heating rate
and the rate of weight change is imposed. It is s
hown in this paper that the reacted fraction at the
maximum reaction rate strongly depends
on the parameters selected for the
Hi-Res
heating
algorithm, what invalidates the use of
the Kissinger method for analysing
Hi-Res
data unless that
the reaction fits a first order kinetic law. Only in this latter case, it has been demonstrated that it is
not required that a constant value of the reacted fr
action at the maximum reaction rate is fulfilled for
determining the activation energy from the Kissi
nger method. In such a case the Kissinger plot
gives the real activation energy, independently of
both the heating schedule used and the value of
the reacted fraction,
α
m
, at the maximum. | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Springer Netherlands | es |
dc.relation.ispartof | Journal of Thermal Analysis and Calorimetry, 94 (2), 427-432. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Kissinger kinetic analysis of data obtained under different heating schedules | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Inorgánica | es |
dc.relation.publisherversion | http://dx.doi.org/10.1007/s10973-008-9200-2 | es |
dc.identifier.doi | 10.1007/s10973-008-9200-2 | es |
idus.format.extent | 6 p. | es |
dc.journaltitle | Journal of Thermal Analysis and Calorimetry | es |
dc.publication.volumen | 94 | es |
dc.publication.issue | 2 | es |
dc.publication.initialPage | 427 | es |
dc.publication.endPage | 432 | es |