dc.creator | Valdivia Giménez, Victoria Esther | es |
dc.creator | Bilbao Bustinza, Nerea | es |
dc.creator | Moya, Juan Francisco | es |
dc.creator | Rosales Barrios, C. | es |
dc.creator | Salvador, Álvaro | es |
dc.creator | Recio Jiménez, Rocío | es |
dc.creator | Fernández Fernández, Inmaculada | es |
dc.creator | Khiar, Noureddine | es |
dc.date.accessioned | 2017-05-17T11:24:45Z | |
dc.date.available | 2017-05-17T11:24:45Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | Valdivia Giménez, V.E., Bilbao Bustinza, N., Moya, J.F., Rosales Barrios, C., Salvador, Á., Recio Jiménez, R.,...,Khiar, N. (2016). Pseudo enantiomeric mixed s/p ligands derived from carbohydrates for the 1,4-addition of phenyl boronic acid to cyclohexenone. RSC Advances, 6 (4), 3041-3047. | |
dc.identifier.issn | 2046-2069 | es |
dc.identifier.uri | http://hdl.handle.net/11441/59961 | |
dc.description.abstract | The application of phosphinite-thioglycosides and phosphine-thioglycosides ligands in the Rh(I)-catalyzed 1,4-addition of phenylboronic acid to cyclohexenone is reported. Among the ligands tested, phosphinite-thioglycoside 3 and phosphine-thioglycoside 10, bearing a 1,2-cis arrangement of the two heteroatoms, have exhibited the best results in terms of reactivity and enantioselectivity. Interestingly, ligands 3 and 10, both derived from D-sugar are able to generate the addition product of the phenylboronic acid to the cyclohexenone with opposite configuration, behaving thus as enantiomers | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Royal Society of Chemistry | es |
dc.relation.ispartof | RSC Advances, 6 (4), 3041-3047. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Pseudo enantiomeric mixed s/p ligands derived from carbohydrates for the 1,4-addition of phenyl boronic acid to cyclohexenone | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Orgánica y Farmacéutica | es |
dc.relation.publisherversion | 10.1039/c5ra10181f | es |
dc.relation.publisherversion | http://doi.org/10.1039/c5ra10181f | es |
dc.identifier.doi | 10.1039/c5ra10181f | es |
idus.format.extent | 7 p. | es |
dc.journaltitle | RSC Advances | es |
dc.publication.volumen | 6 | es |
dc.publication.issue | 4 | es |
dc.publication.initialPage | 3041 | es |
dc.publication.endPage | 3047 | es |