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Phosphinite Thioglycosides Derived from Natural D-Sugars as Useful P/S Ligands for the Synthesis of Both Enantiomers in Palladium-Catalyzed Asymmetric Substitution

 

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Opened Access Phosphinite Thioglycosides Derived from Natural D-Sugars as Useful P/S Ligands for the Synthesis of Both Enantiomers in Palladium-Catalyzed Asymmetric Substitution
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Author: Khiar, Noureddine
Suárez, Belén
Valdivia Giménez, Victoria Esther
Fernández Fernández, Inmaculada
Department: Universidad de Sevilla. Departamento de Química Orgánica y Farmacéutica
Date: 2005
Published in: Synlett, 19, 2963-2967.
Document type: Article
Abstract: Phosphinite thioglycosides I for which a modular synthetic approach is reported, were found highly efficient catalyst precursors for palladium(0)-catalyzed asymmetric substitution. Both enantiomers of the allylated products have been obtained with high ee (up to 96%) using natural sugars as catalyst precursors.
Cite: Khiar, N., Suárez, B., Valdivia Giménez, V.E. y Fernández Fernández, I. (2005). Phosphinite Thioglycosides Derived from Natural D-Sugars as Useful P/S Ligands for the Synthesis of Both Enantiomers in Palladium-Catalyzed Asymmetric Substitution. Synlett, 19, 2963-2967.
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URI: http://hdl.handle.net/11441/43070

DOI: http://dx.doi,org/10.1055/s-2005-918963

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