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Synthesis, structure and reactivity of dimolybdenum complexes with multiple metal-metal bonds

Opened Access Synthesis, structure and reactivity of dimolybdenum complexes with multiple metal-metal bonds
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Autor: Curado Dianez, Natalia
Director: Maya Díaz, Celia María
Carmona Guzmán, Ernesto
Departamento: Universidad de Sevilla. Departamento de Química Inorgánica
Fecha: 2016-01-29
Tipo de documento: Tesis Doctoral
Resumen: At the beginning of this millennium our research group became involved in the study of metal-metal bonds following the unexpected discovery of decamethyldizincocene, [fórmula], the first complex with a direct Zn-Zn bond unsupported by bridging ligands. In the following years other complexes of this type were prepared and characterized. One year after our initial observation of the Zn-Zn bond, the group of Power made a landmark discovery with the characterization of the first complex with a quintuple bond between metal atoms. Considering the previous experience of our group on the coordination and organometallic chemistry of the Group 6 elements molybdenum and tungsten, a systematic study of new binuclear molybdenum compounds featuring a quadruple Mo-Mo bonds was undertaken. The work carried out initially provided the grounds for the PhD Theses of Dr. Mario Carrasco and Dr. Irene Mendoza. The present Thesis completes and extends the research carried out in the chemistry of dimolybdenum...
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Resumen

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Tesis

URI: http://hdl.handle.net/11441/39855

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