Opened Access Imido complexes of vanadium
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Author: Montilla Ramos, Francisco Javier
Pastor Navarro, Antonio
Galindo del Pozo, Agustín
Department: Universidad de Sevilla. Departamento de Química Inorgánica
Date: 1997
Published in: Electronic Conference on Organometallic Chemistry, 30 June - 31 July 1997, 1-5 p.
Document type: Presentation
Abstract: Imido ligands have been widely used as stabilizing ligands in highoxidationstate transition metal complexes. Their chemistry has experienced a remarkable growth due to the role they play in many important reactions. Following our interest in this area, we have extended our recent results in the synthesis of bis(imido) complexes of molybdenum, d0Mo( NR)2, to the related d0 organoimido complexes of vanadium. In this contribution, we describe the synthesis and characterization of several complexes of vanadium containing the imido ligand.
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