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Mostrando ítems 1-5 de 5
Artículo
Alkoxyamine-cyanoborane adducts: Efficient cyanoborane transfer agents
(Royal Society of Chemistry, 2011)
We report the synthesis of the hitherto unknown zwitterionic alkoxyamino cyanoboranes by reduction of O-alkyloximes with sodium cyanoborohydride; unprecedented cyanoboronated N-alkoxyformamidines were also isolated as ...
Artículo
Pyridine–hydrazone ligands in enantioselective palladium-catalyzed Suzuki–Miyaura cross-couplings
(Elsevier, 2016)
The geometries and coordination properties of modular pyridineehydrazone N,N-ligands containing C2- symmetric trans-2,5-diphenylpyrrolidine and trans-2,5-diphenylpiperidine as the terminal dialkylamino units have been ...
Artículo
Metalated Ir–CNP Complexes Containing Imidazolin-2-ylidene and Imidazolidin-2-ylidene Donors – Synthesis, Structure, Luminescence, and Metal–Ligand Cooperative Reactivity
(Wiley-Blackwell, 2020)
The iridium complex 1 based on a metalated CNP ligand containing an imidazolin-2-ylidene fragment has been prepared by treatment of the ligand precursor 4 with Ag2O followed by reaction with [IrCl(COE)2]2. The chlorohydride ...
Artículo
Cu(I) and Ag(I) complexes of two sterically demanding Xylyl-Substituted phosphine Ligands: Synthesis, Characterization, and structural examination
(Elsevier, 2023)
Two sterically demanding tertiary phosphines, PiPr2Xyl and PtBu2Xyl, (Xyl = 2,6-dimethylphenyl), the latter reported here for the first time, have been used to synthesize a series of dinuclear complexes of the general ...
Artículo
Catalytic Nitrous Oxide Reduction with H2 Mediated by Pincer Ir Complexes
(American Chemical Society, 2022)
Reduction of nitrous oxide (N2O) with H2 to N2 and water is an attractive process for the decomposition of this greenhouse gas to environmentally benign species. Herein, a series of iridium complexes based on ...