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Artículo
Selective CO methanation with structured RuO2/Al2O3 catalysts
(Elsevier, 2018)
Active and selective structured RuO2/Al2O3 catalysts for CO methanation using a flow simulating CO2-rich reformate gases from WGS and PROX units (H2 excess, CO2 presence and 300 ppm CO concentration) were prepared. Both, ...
Artículo
Anisotropic lattice expansion determined during flash sintering of BiFeO3 by in-situ energy-dispersive X-ray diffraction
(Elsevier, 2019)
BiFeO3 has a Curie temperature (TC) of 825 °C, making it difficult to sinter using conventional methods while maintaining the purity of the material, as unavoidably secondary phases appear at temperatures above Tc. Flash ...
Artículo
Lithium Di-‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-‐Mo Quadruple Bonds and Bridging Methyl Groups
(American Chemical Society, 2015)
New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents a bidentate aminopyridinate or amidinate ligand that bridges the quadruply bonded molybdenum ...
Artículo
Growth of nanocolumnar thin films on patterned substrates at oblique angles
(Wiley-VCH Verlag, 2019)
The influence of one dimensional substrate patterns on the nanocolumnar growth of thin films deposited by magnetron sputtering at oblique angles is theoretically and experimentally studied. A well‐established growth model ...
Artículo
A direct in situ observation of water-enhanced proton conductivity of Eu-doped ZrO2: Effect on WGS reaction
(Elsevier, 2018)
Eu-doped ZrO2 solid solutions have been synthesized in order to prepare proton conductors as water-enhancer additives for the WGS reaction. Elemental characterization has been carried out revealing homogeneous ...
Artículo
Pt/CePO4 catalysts for the WGS reaction: influence of the water-supplier role of the support on the catalytic performance
(Royal Society of Chemistry, 2018)
For Pt catalysts which have demonstrated great activity for the WGS reaction, the activation of water is described as the rate-limiting step. Such limitation could be overcome through the design of supports able to supply ...
Artículo
New single-phase, white-light-emitting phosphors based on δ-Gd 2Si2O7 for solid-state lighting
(American Chemical Society, 2014)
Two new white-light (WL)-emitting phosphors (δ-Gd2Si 2O7:Dy and δ-Gd2Si2O 7:Eu,Tb) have been synthesized by the sol-gel method. The Gd-Ln 3+ (Ln3+= Dy3+, Tb3+, Eu 3+) energy-transfer band has been used to excite both ...
Artículo
Non-heteroatom-substituted alkylidene complexes of groups 10 and 11
(Elsevier, 2018)
This review aims to offer a detailed summary of the discoveries regarding non-heteroatom-substituted alkylidenes of group 10 and 11 metals that have appeared in the literature since the first isolable representative of ...
Artículo
Effect of clays and metal containers in retaining Sm3+ and ZrO2+ and the process of reversibility
(Walter de Gruyter, 2014)
Knowledge and understanding about radionuclides retention processes on the materials composing the engineered barrier (clay mineral and metallic container waste) are required to ensure the safety and the long-term performance ...