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Artículo
Supported σ-Complexes of Li−C Bonds from Coordination of Monomeric Molecules of LiCH3, LiCH2CH3 and LiC6H5 to Mo≣Mo Bonds
(German Chemical Society, 2022)
LiCH3 and LiCH2CH3 react with the complex [Mo2(H)2(μ-AdDipp2)2(thf)2] (1⋅thf) with coordination of two molecules of LiCH2R (R=H, CH3) and formation of complexes [Mo2{μ-HLi(thf)CH2R}2(AdDipp2)2], 5⋅LiCH3 and 5⋅LiCH2CH3, ...
Tesis Doctoral
Artículo
Lithium Di-‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-‐Mo Quadruple Bonds and Bridging Methyl Groups
(American Chemical Society, 2015)
New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents a bidentate aminopyridinate or amidinate ligand that bridges the quadruply bonded molybdenum ...
Tesis Doctoral
Compuestos de dinitrógeno, etileno y óxido nítrico de elementos de las series de transición: Derivados de Mo, W e Ir
(1991-09-26)
CONCLUSIONES: 1. El compuesto [Mo(N2)2(PEt3)3]2(µ-N2) presenta gran tendencia a la sustitución de los ligandos trietilfosfina, probablemente debido a la alta densidad electrónica existente sobre el centro metálico, generando ...
Artículo
Non-heteroatom-substituted alkylidene complexes of groups 10 and 11
(Elsevier, 2018)
This review aims to offer a detailed summary of the discoveries regarding non-heteroatom-substituted alkylidenes of group 10 and 11 metals that have appeared in the literature since the first isolable representative of ...
Artículo
Síntesis, propiedades térmicas, espectroscópicas y magnéticas de los compuestos de coordinación de Mn(II), Co(II), Ni(II) y Cu(II) con el ácido trans-1,2-diaminociclohexano tetraacético (ADCT)
(Real Sociedad Española de Física y Química, 1978)
Tesis Doctoral
Contribución a la química organometálica de los elementos niquel e iridio
(1978-12)
A) se han sintetizado y caracterizado diversos derivados dialquilicos de ni(ii) que contienen al radical ch2sime2ph. Los compuestos obtenidos, de composición nir2(l-l), se estabilizan por la presencia de ligandos quelatantes ...
Tesis Doctoral
Artículo
Large-scale preparation and labelling reactions of deuterated silanes
(John Wiley & Sons, 2012)
A catalytic synthesis of deuterated silanes SiEt3D, SiMe2PhD and SiPh2D2 is reported that allows their facile generation in a 3–4 g scale, utilizing D2 (0.5 bar) as the hydrogen isotope source and low catalyst loadings ...
Artículo
Synthesis and structural characterization of a binuclear iridium complex with bridging, bidentate N-heterocyclic carbene coordination of 2, 2 ':6 ', 2''-terpyridine
(Royal Society of Chemistry, 2009)
Thermal activation of terpyridine in the presence of an unsaturated Ir(III) fragment stabilized by a hydrotris(pyrazolyl) borate ligand gives rise to mononuclear complex 2 and binuclear 3, in which the polypyridine ...