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Artículo
Homochiral imidazolium-based dicarboxylate silver(i) compounds: synthesis, characterisation and antimicrobial properties
(Royal Society of Chemistry, 2022-03)
Complexes [Ag(LR)], 2 (LR = 2,2′-(imidazolium-1,3-diyl)di(2-alkylacetate)), were prepared by treatment of compounds HLR, 1, with Ag2O. They were characterised by analytical, spectroscopic (IR, 1H and 13C NMR and polarimetry) ...
Ponencia
Imido complexes of vanadium
(1997)
Imido ligands have been widely used as stabilizing ligands in highoxidationstate transition metal complexes. Their chemistry has experienced a remarkable growth due to the role they play in many important reactions. ...
Artículo
Oxidoperoxidomolybdenum(VI) complexes with acylpyrazolonate ligands: synthesis, structure and catalytic properties
(The Royal Society of Chemistry, 2018)
Oxidoperoxido–molybdenum(VI) complexes containing acylpyrazolonate ligands were obtained by reaction of [Mo(O)(O)2(H2O)n] with the corresponding acylpyrazolone compounds HQR. Complexes Ph4P[Mo(O)(O2)2(QR)] (R = neopentyl, ...
Artículo
Oil shale phenol-derived aerogels as supports for palladium nanoparticles
(2009)
Palladium hexafluoroacetylacetonate [Pd(C4HF6O)2], which is both soluble and easily reducible in supercritical carbon dioxide, was used to impregnate the porous structure of carbon aerogels based on phenolic compounds ...
Artículo
Influence of N-donor bases and the solvent in oxodiperoxomolybdenum catalysed olefin epoxidation with hydrogen peroxide in ionic liquids
(Royal Society of Chemistry, 2011)
Biphasic catalytic olefin epoxidation systems consisting of oxodiperoxomolybdenum catalysts in 1- n -alkyl-3-methylimidazolium hexafluorophosphate ionic liquid (IL) media with aqueous hydrogen peroxide oxidant were optimised ...
Artículo
Molybdenum-catalyzed enantioselective sulfoxidation controlled by a nonclassical hydrogen bond between coordinated chiral imidazolium-based dicarboxylate and peroxido ligands
(MDPI, 2018)
Chiral alkyl aryl sulfoxides were obtained by molybdenum-catalyzed oxidation of alkyl aryl sulfides with hydrogen peroxide as oxidant in mild conditions with high yields and moderate enantioselectivities. The asymmetry is ...
Artículo
Synthesis and characterization of chiral bidentate bis(N-heterocyclic carbene)-carboxylate palladium and nickel complexes
(Elsevier, 2022)
Complexes [Pd{(S)-NHCMes,R}2] (R = Me, 2a; iPr, 2b; iBu, 2c) and [Pd{(R)-NHCMes,Me}2] (2a’) were prepared by reaction of the corresponding imidazolium precursor [ImMes,R] (namely (S)–2-alkyl(3-mesityl-1H-imidazol-3- iu ...
Tesis Doctoral
Procesos de oxidación selectiva catalizados por oxidoperoxidocomplejos de molibdeno usando criterios de química sostenible
(2017-05-19)
En la presente Tesis Doctoral se pretende efectuar una contribución en el área de la Química Verde a través del estudio y desarrollo de nuevos sistemas catalíticos que son activos en diversas reacciones de oxidación selectiva ...
Artículo
Influence of the ionic liquid presence on the selective oxidation of glucose over molybdenum based catalysts
(Elsevier, 2016-12-01)
Two different approaches are proposed in this work in order to study the influence of the ionic liquid presence in the reaction of glucose oxidation by H2O2 in mild conditions. The ionic liquids are applied either as a ...
Tesis Doctoral
Procesos de oxidación selectiva catalizados por complejos metálicos en medios no convencionales: Hacia una química sostenible
(2010)
La presente memoria pretende efectuar una contribución en el área de la Química Verde o Química Sostenible en lo que se refiere a la utilización de medios no convencionales como disolventes en Catálisis Homogénea. En ...