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Listar por autor "López Serrano, Joaquín"
Mostrando ítems 21-40 de 49
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Artículo
Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes
Rivada Wheelaghan, Orestes; Roselló Merino, Marta; Díez, Josefina; Maya Díaz, Celia María; López Serrano, Joaquín; Conejero, Salvador (American Chemical Society, 2014)Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully ...
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Artículo
From cyclic amines and acetonitrile to amidine zinc(II) complexes
Podjed, Nina; Modec, Barbara; Alcaide, María M.; López Serrano, Joaquín (Royal Society of Chemistry, 2020)A seemingly simple combination of [Zn(quin)2(H2O)] (quin− = quinaldinate) and a selected secondary cyclic amine, piperidine ...
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Artículo
Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir–CNP* pincer complex. Water influence on the catalytic activity
Sánchez Mellado, Práxedes; Hernández Juárez, Martín; Rendón Márquez, Nuria; López Serrano, Joaquín; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2018)Iridium complexes based on deprotonated lutidine-derived CNP* pincers 2a/2b selectively catalyzed the hydroboration of ...
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Artículo
Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment
Hernández Juárez, Martín; López Serrano, Joaquín; González Herrero, P.; Rendón Márquez, Nuria; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2018)An iridium complex featuring a metalated lutidine-derived CNP ligand reacts with KOt Bu to yield a dimeric species with ...
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Artículo
Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
Sánchez Mellado, Práxedes; Hernández Juárez, Martín; Rendón Márquez, Nuria; López Serrano, Joaquín; López Santos, Laura; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2020)Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts ...
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Artículo
Ir-Catalyzed Atroposelective Desymmetrization of Heterobiaryls: Hydroarylation of Vinyl Ethers and Bicycloalkenes
Romero Arenas, Antonio; Hornillos, Valentín; Iglesias Sigüenza, Francisco Javier; Fernández Fernández, Rosario Fátima; López Serrano, Joaquín; Ros, Abel; Lassaletta, José M. (American Chemical Society, 2020)A highly regio-, diastereo-, and enantioselective, scalable Ir-catalyzed hydroarylation of electron-rich acyclic and ...
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Artículo
Ligand Rearrangement and Hemilability in R hodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphines
Moreno Díaz, Juan José; Fernández Espada, María; Krüger, Eric; López Serrano, Joaquín; Campos, Jesús; Carmona Guzmán, Ernesto (Wiley, 2018)We describe the synthesis of a series of cationic rhodium(I) and iridium(I) compounds stabilized by ...
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Artículo
Lithium Di-‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-‐Mo Quadruple Bonds and Bridging Methyl Groups
Curado, Natalia; Carrasco, Mario; Álvarez González, Eleuterio; Maya Díaz, Celia María; Peloso, Riccardo; Rodríguez, Amor; López Serrano, Joaquín; Carmona Guzmán, Ernesto (American Chemical Society, 2015)New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents ...
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Artículo
Mechanism of Dihydrogen Splitting by An Apparent Bimetallic Frustrated Lewis Pair based on Ir(III)/Pt(0)
Moreno Díaz, Juan José; Pita Milleiro, Alejandra; Luque Gómez, Ana; Espada, María F.; López Serrano, Joaquín; Campos, Jesús (Wiley-Blackwell, 2023)The incorporation of transition metals into frustrated Lewis pairs (FLPs) offers multiple opportunities for bond activation ...
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Artículo
Mechanistic Studies on the Selective Reduction of CO2 to the Aldehyde Level by a PBP-Supported Nickel Complex
Ríos Moreno, Pablo; Rodríguez, Amor; López Serrano, Joaquín (American Chemical Society, 2016)This work describes a thorough investigation of the mechanism of a highly selective hydrosilylation of CO2 to the formaldehyde ...
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Artículo
Metal-only Lewis Pairs of Rhodium with s, p and d-Block Metals
Bajo Velázquez, Sonia; González Alférez, Macarena; Moreno Alcaide, María; López Serrano, Joaquín; Campos, Jesús (Wiley, 2020)Metal-only Lewis pairs (MOLPs) in which the two metal fragments are solely connected by a dative M→M bond represent ...
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Artículo
Metalated Ir–CNP Complexes Containing Imidazolin-2-ylidene and Imidazolidin-2-ylidene Donors – Synthesis, Structure, Luminescence, and Metal–Ligand Cooperative Reactivity
Hernández Juárez, Martín; Sánchez, Práxedes; López Serrano, Joaquín; Lara Muñoz, Patricia; González Herrero, Pablo; Rendón Márquez, Nuria; Álvarez, Eleuterio; Paneque, Margarita; Suárez, Andrés (Wiley-Blackwell, 2020)The iridium complex 1 based on a metalated CNP ligand containing an imidazolin-2-ylidene fragment has been prepared by ...
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Artículo
Methyl Complexes of the Transition Metals
Campos, Jesús; López Serrano, Joaquín; Peloso, Riccardo; Carmona Guzmán, Ernesto (John Wiley & Sons, 2016)Organometallic chemistry can be considered as a wide area of knowledge that combines concepts of classic organic chemistry, ...
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Artículo
New Phosphonite Ligands with High Steric Demand and Low Basicity: Synthesis, Structural Properties and Cyclometalated Complexes of Pt(II)
Alcaide, María M.; Pugliesi, Matteo; Álvarez, Eleuterio; López Serrano, Joaquín; Peloso, Riccardo (Multidisciplinary Digital Publishing Institute (MDPI), 2022)Two phosphonite ligands bearing the highly sterically demanding 2,6-bis (2,6-dimethylphenyl)phenyl group (ArXyl2), ...
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Artículo
Nitrous oxide activation by picoline-derived Ni-CNP hydrides
Bermejo, José; Ortega Lepe, Isabel; López Santos, Laura; Rendón Márquez, Nuria; López Serrano, Joaquín; Álvarez, Eleuterio; Suárez, Andrés (Royal Society of Chemistry, 2024-01-10)Oxygen atom transfer (OAT) from N2O to the Ni–H bond of protonresponsive picoline-derived CNP nickel complexes has been ...
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Tesis Doctoral
Nuevos ligandos fosforados voluminosos y sus complejos mono- y dinucleares de platino: síntesis, propiedades y estudios computacionales
Moreno Alcaide, María (2023-06-16)Esta tesis doctoral tiene como hilo conductor los ligandos fosforados consustituyentes voluminosos, tratando de la síntesis ...
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Artículo
Quadruply bonded dimolybdenum complexes with highly unusual geometries and vacant coordination sites
Carrasco, Mario; Faust, Michelle; Peloso, Riccardo; Rodríguez Iglesias, María Amor; López Serrano, Joaquín; Álvarez González, Eleuterio; Maya Díaz, Celia María; Power, Philip P.; Carmona Guzmán, Ernesto (Royal Society of Chemistry (Great Britain), 2012)New quadruply bonded dimolybdenum complexes of the terphenyl ligand Ar Xyl2 (Ar Xyl2 = C 6H 3-2,6-(C 6H 3-2,6-Me 2) 2) ...
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Artículo
Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions
Pérez Jiménez, Marina; Campos Manzano, Jesús; López Serrano, Joaquín; Carmona Guzmán, Ernesto (Royal Society of Chemistry, 2018)Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford ...
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Artículo
Rhodium(I) Complexes with Ligands Based on N-Heterocyclic Carbene and Hemilabile Pyridine Donors as Highly E Stereoselective Alkyne Hydrosilylation Catalysts
Morales Cerón, Judith; Lara Muñoz, Patricia; López Serrano, Joaquín; López Santos, Laura; Salazar Pereda, Verónica; Álvarez González, Eleuterio; Suárez Escobar, Andrés Luis (American Chemical Society, 2017)Cationic rhodium(I) complexes containing picolyl-NHC (NHC = N-heterocyclic carbene) ligands that differ in the substitution ...
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Artículo
Ruthenium(II) Complexes Containing Lutidine-derived Pincer CNC Ligands: Synthesis, Structure and Catalytic Hydrogenation of C=N bonds
Hernández Juárez, Martín; López Serrano, Joaquín; Lara Muñoz, Patricia; Morales Cerón, Judith; Vaquero Gutiérrez, Mónica; Álvarez González, Eleuterio; Salazar Pereda, Verónica; Suárez Escobar, Andrés Luis (Wiley-Blackwell, 2015)A series of Ru complexes containing lutidine‐derived pincer CNC ligands have been prepared by transmetalation with the ...