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dc.creatorBenítez Jiménez, José Jesúses
dc.creatorSalmerón, Miqueles
dc.date.accessioned2018-04-04T15:37:05Z
dc.date.available2018-04-04T15:37:05Z
dc.date.issued2006
dc.identifier.citationBenítez Jiménez, J.J. y Salmerón, M. (2006). The influence of chain length and ripening time on the self-assembly of alkylamines on mica. Journal of Chemical Physics, 125 (4), 1-5.
dc.identifier.issn0021-9606 (impreso)es
dc.identifier.issn1089-7690 (electrónico)es
dc.identifier.urihttps://hdl.handle.net/11441/71774
dc.description.abstractThe influence of chain length and ripening time on the self-assembly of tetradecyl C 14 , hexadecyl C 16 , and octadecylamine C 16 on mica has been studied by atomic force microscopy. The overall process can be described in three stages characterized by different time scales. First, alkylamine molecules adsorb in a process controlled by water mediated interactions of the NH 2 head groups and mica. Second, surface diffusion and aggregation into islands takes place, driven by energy interactions between alkyl chains. The third stage consists of a progressive tilt of the self-assembled molecules towards the surface, driven by relaxation of the electrostatic repulsion between protonated amino groups due to water uptake from atmosphere.es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherAmerican Institute of Physicses
dc.relation.ispartofJournal of Chemical Physics, 125 (4), 1-5.
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.titleThe influence of chain length and ripening time on the self-assembly of alkylamines on micaes
dc.typeinfo:eu-repo/semantics/articlees
dc.type.versioninfo:eu-repo/semantics/acceptedVersiones
dc.rights.accessrightsinfo:eu-repo/semantics/openAccesses
dc.relation.publisherversionhttp://dx.doi.org/10.1063/1.2221692es
dc.identifier.doi10.1063/1.2221692es
idus.format.extent5 p.es
dc.journaltitleJournal of Chemical Physicses
dc.publication.volumen125es
dc.publication.issue4es
dc.publication.initialPage1es
dc.publication.endPage5es

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