dc.creator | Sánchez Jiménez, Pedro Enrique | es |
dc.creator | Perejón Pazo, Antonio | es |
dc.creator | Criado Luque, José Manuel | es |
dc.creator | Diánez Millán, María Jesús | es |
dc.creator | Pérez Maqueda, Luis Allan | es |
dc.date.accessioned | 2018-04-03T16:47:39Z | |
dc.date.available | 2018-04-03T16:47:39Z | |
dc.date.issued | 2010 | |
dc.identifier.citation | Sánchez Jiménez, P.E., Perejón Pazo, A., Criado Luque, J.M., Diánez Millán, M.J. y Pérez Maqueda, L.A. (2010). Kinetic model for thermal dehydrochlorination of poly(vinyl chloride). Polymer, 51, 3998-4007. | |
dc.identifier.issn | 0032-3861 | es |
dc.identifier.uri | https://hdl.handle.net/11441/71651 | |
dc.description.abstract | In this paper, a novel method for calculating degradation kinetics is presented. The method has been applied to the thermal dehydrochlorination of two different samples of PVC. It has been observed that this dehydrochlorination is complex and involves two different processes. A model that accounts for the entire dehydrochlorination is proposed. This model involves nucleation and growth and diffusion controlled mechanisms. The kinetic parameters are obtained from linear heating rate, isothermal and sample controlled thermal analysis experiments. Kinetic results obtained from the macroscopic thermal analysis measurements demonstrate the correlation between the kinetics of the thermal dehydrochlorination of PVC and the structure of this macromolecule. | es |
dc.description.sponsorship | Junta de Andalucía TEP-03002 | es |
dc.description.sponsorship | Ministerio de Ciencia e Innovación MAT 2008-06619/MAT | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Elsevier | es |
dc.relation.ispartof | Polymer, 51, 3998-4007. | |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Kinetic model | es |
dc.subject | Kinetics | es |
dc.subject | Nucleation and growth | es |
dc.subject | Diffusion | es |
dc.subject | Dehydrochlorination | es |
dc.subject | PVC | es |
dc.title | Kinetic model for thermal dehydrochlorination of poly(vinyl chloride) | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.relation.projectID | TEP-03002 | es |
dc.relation.projectID | MAT 2008-06619/MAT | es |
dc.relation.publisherversion | http://dx.doi.org/10.1016/j.polymer.2010.06.020 | es |
dc.identifier.doi | 10.1016/j.polymer.2010.06.020 | es |
idus.format.extent | 36 p. | es |
dc.journaltitle | Polymer | es |
dc.publication.volumen | 51 | es |
dc.publication.initialPage | 3998 | es |
dc.publication.endPage | 4007 | es |
dc.contributor.funder | Junta de Andalucía | |
dc.contributor.funder | Ministerio de Ciencia e Innovación (MICIN). España | |