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Kinetic model for thermal dehydrochlorination of poly(vinyl chloride)

dc.creatorSánchez Jiménez, Pedro Enriquees
dc.creatorPerejón Pazo, Antonioes
dc.creatorCriado Luque, José Manueles
dc.creatorDiánez Millán, María Jesúses
dc.creatorPérez Maqueda, Luis Allanes
dc.date.accessioned2018-04-03T16:47:39Z
dc.date.available2018-04-03T16:47:39Z
dc.date.issued2010
dc.identifier.citationSánchez Jiménez, P.E., Perejón Pazo, A., Criado Luque, J.M., Diánez Millán, M.J. y Pérez Maqueda, L.A. (2010). Kinetic model for thermal dehydrochlorination of poly(vinyl chloride). Polymer, 51, 3998-4007.
dc.identifier.issn0032-3861es
dc.identifier.urihttps://hdl.handle.net/11441/71651
dc.description.abstractIn this paper, a novel method for calculating degradation kinetics is presented. The method has been applied to the thermal dehydrochlorination of two different samples of PVC. It has been observed that this dehydrochlorination is complex and involves two different processes. A model that accounts for the entire dehydrochlorination is proposed. This model involves nucleation and growth and diffusion controlled mechanisms. The kinetic parameters are obtained from linear heating rate, isothermal and sample controlled thermal analysis experiments. Kinetic results obtained from the macroscopic thermal analysis measurements demonstrate the correlation between the kinetics of the thermal dehydrochlorination of PVC and the structure of this macromolecule.es
dc.description.sponsorshipJunta de Andalucía TEP-03002es
dc.description.sponsorshipMinisterio de Ciencia e Innovación MAT 2008-06619/MATes
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherElsevieres
dc.relation.ispartofPolymer, 51, 3998-4007.
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectKinetic modeles
dc.subjectKineticses
dc.subjectNucleation and growthes
dc.subjectDiffusiones
dc.subjectDehydrochlorinationes
dc.subjectPVCes
dc.titleKinetic model for thermal dehydrochlorination of poly(vinyl chloride)es
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/submittedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.relation.projectIDTEP-03002es
dc.relation.projectIDMAT 2008-06619/MATes
dc.relation.publisherversionhttp://dx.doi.org/10.1016/j.polymer.2010.06.020es
dc.identifier.doi10.1016/j.polymer.2010.06.020es
idus.format.extent36 p.es
dc.journaltitlePolymeres
dc.publication.volumen51es
dc.publication.initialPage3998es
dc.publication.endPage4007es
dc.contributor.funderJunta de Andalucía
dc.contributor.funderMinisterio de Ciencia e Innovación (MICIN). España

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