dc.creator | Khiar, Noureddine | es |
dc.creator | Navas, Raquel | es |
dc.creator | Álvarez González, Eleuterio | es |
dc.creator | Fernández Fernández, Inmaculada | es |
dc.date.accessioned | 2016-07-05T09:49:33Z | |
dc.date.available | 2016-07-05T09:49:33Z | |
dc.date.issued | 2008 | |
dc.identifier.citation | Khiar, N., Navas, R., Álvarez González, E. y Fernández Fernández, I. (2008). New sulfur-phosphine ligands derived from sugars: synthesis and application in palladium-catalyzed allylic alkylation and in rhodium asymmetric hydrogenation. Arkivoc, 2008 (8), 211-224. | |
dc.identifier.issn | 1424-6376 | es |
dc.identifier.uri | http://hdl.handle.net/11441/43143 | |
dc.description.abstract | An efficient route to mixed phosphine / thioglycoside ligands type IV starting from glucose pentaacetate is reported. In only five steps the key epoxide 6 has been obtained in high yield and its structure determined by X-ray analysis. The ring opening of the tert-butyl 4,6-O-benzylidene- 2,3-anhydro-1-thio-β-D-allopyranoside 6 with diphenylphosphinyl lithium afforded the desired ligand as a single diastereoisomer. The prepared compounds act as a bidentate ligands as shown by X-ray analysis of the Rh(I)-complex 12. Preliminary results on the behaviour of these ligands in Pd(0)-catalyzed allylic alkylation, and in Rh(I)-catalyzed enamide hydrogenation are also reported. | es |
dc.description.sponsorship | Dirección General de Investigaciones Científicas y Técnicas CTQ2006- 15515-CO2-01 y CTQ2007-61185 | es |
dc.description.sponsorship | Junta de Andalucía P06-FQM-01852 y P07- FQM-2774 | es |
dc.description.sponsorship | Fundación Ramón Areces | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Arkat USA | es |
dc.relation.ispartof | Arkivoc, 2008 (8), 211-224. | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Asymmetric hydrogenation | es |
dc.subject | Carbohydrates | es |
dc.subject | Pd-catalyzed allylic alkylation | es |
dc.subject | S-P ligands | es |
dc.title | New sulfur-phosphine ligands derived from sugars: synthesis and application in palladium-catalyzed allylic alkylation and in rhodium asymmetric hydrogenation | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Orgánica y Farmacéutica | es |
dc.relation.projectID | CTQ2006- 15515-CO2-01 | es |
dc.relation.projectID | CTQ2007-61185 | es |
dc.relation.projectID | P06-FQM-01852 | es |
dc.relation.projectID | P07- FQM-2774 | es |
dc.relation.publisherversion | http://dx.doi.org/10.3998/ark.5550190.0009.817 | |
dc.identifier.doi | 10.3998/ark.5550190.0009.817 | |
idus.format.extent | 14 p. | es |
dc.journaltitle | Arkivoc | es |
dc.publication.volumen | 2008 | es |
dc.publication.issue | 8 | es |
dc.publication.initialPage | 211 | es |
dc.publication.endPage | 224 | es |
dc.identifier.idus | https://idus.us.es/xmlui/handle/11441/43143 | |