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Proline-coated gold nanoparticles as a highly efficient nanocatalyst for the enantioselective direct aldol reaction in water

dc.creatorKhiar, Noureddinees
dc.creatorNavas, Raqueles
dc.creatorElhalem, Eleonoraes
dc.creatorValdivia Giménez, Victoria Estheres
dc.creatorFernández Fernández, Inmaculadaes
dc.date.accessioned2016-06-23T10:22:41Z
dc.date.available2016-06-23T10:22:41Z
dc.date.issued2013
dc.identifier.citationKhiar, N., Navas, R., Elhalem, E., Valdivia Giménez, V.E. y Fernández Fernández, I. (2013). Proline-coated gold nanoparticles as a highly efficient nanocatalyst for the enantioselective direct aldol reaction in water. RSC Advances, 3 (12), 3861-3864.
dc.identifier.issn2046-2069es
dc.identifier.urihttp://hdl.handle.net/11441/42702
dc.description.abstractReported is an efficient approach to the synthesis of water-soluble proline-coated gold nanoparticles through a place exchange reaction between pentanethiolate stabilized gold nanoparticles and a proline-tethered amphiphilic thiol. Preliminary studies show that the nanocatalyst is highly active in an enamine type aldolisation leading to the desired product with nearly perfect diastereoselectivity and enantioselectivity using water as an innocuous solventes
dc.description.sponsorshipMinisterio de Economía y Competitividad CTQ2010-21755-CO2-00es
dc.description.sponsorshipJunta de Andalucía P07-FQM-2774es
dc.formatapplication/pdfes
dc.language.isoenges
dc.publisherRoyal Society of Chemistryes
dc.relation.ispartofRSC Advances, 3 (12), 3861-3864.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectCondensation reactionses
dc.subjectEnantioselectivityes
dc.subjectMetal nanoparticleses
dc.titleProline-coated gold nanoparticles as a highly efficient nanocatalyst for the enantioselective direct aldol reaction in wateres
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Orgánica y Farmacéuticaes
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/CTQ2010-21755-CO2-00es
dc.relation.projectIDP07-FQM-2774es
dc.relation.publisherversionhttp://dx.doi.org/10.1039/c3ra22955fes
dc.identifier.doi10.1039/c3ra22955fes
idus.format.extent4 p.es
dc.journaltitleRSC Advanceses
dc.publication.volumen3es
dc.publication.issue12es
dc.publication.initialPage3861es
dc.publication.endPage3864es
dc.identifier.idushttps://idus.us.es/xmlui/handle/11441/42702
dc.contributor.funderMinisterio de Economía y Competitividad (MINECO). España
dc.contributor.funderJunta de Andalucía

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