dc.creator | García Haro, Pedro | |
dc.creator | Ollero de Castro, Pedro Antonio | |
dc.creator | Vidal Barrero, Fernando | |
dc.creator | Villanueva Perales, Ángel Luis | |
dc.date.accessioned | 2016-02-17T10:45:48Z | |
dc.date.available | 2016-02-17T10:45:48Z | |
dc.date.issued | 2013 | |
dc.identifier.citation | García Haro, P., Ollero de Castro, P.A., Vidal Barrero, F. y Villanueva Perales, Á.L. (2013). Potential Routes for Thermochemical Biorefineries. | |
dc.identifier.issn | 1932-104X | es |
dc.identifier.uri | http://hdl.handle.net/11441/34967 | |
dc.description.abstract | This critical review focuses on potential routes for the multi-production of chemicals and fuels in the framework of thermochemical biorefineries. The up-to-date research and development in this field has been limited to BTL/G (biomass-to-liquids/gases) studies, where biomass-derived synthesis gas (syngas) is converted into a single product with/without the co-production of electricity and heat. Simultaneously, the interest on biorefineries is growing but mostly refers to the biochemical processing of biomass. However, thermochemical biorefineries (multi-product plants using thermo-chemical processing of biomass) are still the subject of few studies. This scarcity of studies could be attributed to the limitations of current designs of BTL/G for multi-production and the limited number of considered routes for syngas conversion. The use of a platform chemical (an intermediate) brings new opportunities to the design of process concepts, since unlike BTL/G processes they are not restricted to the conversion of syngas in a single-reaction system. Most of the routes presented here are based on old-fashioned and new routes for the processing of coal- and natural-gas-derived syngas, but they have been re-thought for the use of biomass and the multi-production plants (thermochemical biorefinery). The considered platform chemicals are methanol, DME, and ethanol, which are the common products from syngas in BTL/G studies. Important keys are given for the integration of reviewed routes into the design of thermochemical biorefineries, in particular for the selection of the mix of co-products, as well as for the sustainability (co-feeding, CO2 capture, and negative emissions). | es |
dc.description.sponsorship | Ministerio de Educación FPU Program (AP2010-0119) | es |
dc.description.sponsorship | Ministerio de Economía y Competitividad ENE2012-31598 | es |
dc.format | application/pdf | es |
dc.language.iso | eng | es |
dc.publisher | Wiley | es |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | Thermochemical biorefinery | es |
dc.subject | Methanol | es |
dc.subject | Dimethyl ether (DME) | es |
dc.subject | Ethanol | es |
dc.subject | Butanol | es |
dc.subject | Acetic anhydride | es |
dc.title | Potential Routes for Thermochemical Biorefineries | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/submittedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Ingeniería Química y Ambiental | es |
dc.relation.projectID | info:eu-repo/grantAgreement/MINECO/ENE2012-31598 | es |
dc.relation.publisherversion | 10.1002/bbb.1409 | es |
dc.identifier.doi | http://dx.doi.org/10.1002/bbb.1409 | es |
dc.identifier.idus | https://idus.us.es/xmlui/handle/11441/34967 | |
dc.contributor.funder | Ministerio de Educación. España | |
dc.contributor.funder | Ministerio de Economía y Competitividad (MINECO). España | |