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N -Isopropylsulfinylimines vs. N-tert -butylsulfinylimines in the stereoselective synthesis of sterically hindered amines: An improved synthesis of enantiopure (R)- And (S)-rimantadine and the trifluoromethylated analogues
dc.creator | Moreno Rodríguez, Nazaret | es |
dc.creator | Recio Jiménez, Rocío | es |
dc.creator | Valdivia Giménez, Victoria Esther | es |
dc.creator | Khiar, Noureddine | es |
dc.creator | Fernández Fernández, Inmaculada | es |
dc.date.accessioned | 2024-01-16T09:07:37Z | |
dc.date.available | 2024-01-16T09:07:37Z | |
dc.date.issued | 2019-11-04 | |
dc.identifier.citation | Moreno Rodríguez, N., Recio Jiménez, R., Valdivia Giménez, V.E., Khiar, N. y Fernández Fernández, I. (2019). N -Isopropylsulfinylimines vs. N-tert -butylsulfinylimines in the stereoselective synthesis of sterically hindered amines: An improved synthesis of enantiopure (R)- And (S)-rimantadine and the trifluoromethylated analogues. Organic and Biomolecular Chemistry, 17 (46), 9854-9858. https://doi.org/10.1039/C9OB02241D. | |
dc.identifier.issn | 1477-0520 | es |
dc.identifier.issn | 1477-0539 | es |
dc.identifier.uri | https://hdl.handle.net/11441/153425 | |
dc.description.abstract | An improved fully stereoselective synthesis of both enantiomers of rimantadine and its trifluoromethylated analogues has been developed, using N-isopropylsulfinylimines as a starting chiral material, proving the superiority of the isopropyl group as a chiral inducer over the tert-butyl group in the case of hindered N-sulfinylimines. | es |
dc.description.sponsorship | Ministerio de Economía y Competitividad de España (MEC) - CTQ2016-78580-C2-2R | es |
dc.format | application/pdf | es |
dc.format.extent | 5 p. | es |
dc.language.iso | spa | es |
dc.publisher | Royal Society of Chemistry | es |
dc.relation.ispartof | Organic and Biomolecular Chemistry, 17 (46), 9854-9858. | |
dc.title | N -Isopropylsulfinylimines vs. N-tert -butylsulfinylimines in the stereoselective synthesis of sterically hindered amines: An improved synthesis of enantiopure (R)- And (S)-rimantadine and the trifluoromethylated analogues | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/acceptedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Química Orgánica y Farmacéutica | es |
dc.relation.projectID | CTQ2016-78580-C2-2R | es |
dc.relation.publisherversion | DOI https://doi.org/10.1039/C9OB02241D | es |
dc.identifier.doi | 10.1039/C9OB02241D | es |
dc.journaltitle | Organic and Biomolecular Chemistry | es |
dc.publication.volumen | 17 | es |
dc.publication.issue | 46 | es |
dc.publication.initialPage | 9854 | es |
dc.publication.endPage | 9858 | es |
dc.contributor.funder | Ministerio de Economía y Competitividad (MINECO). España | es |
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