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dc.creatorEscobar-Galindo, Ramónes
dc.creatorVeen, A. vanes
dc.creatorSchut, Henkes
dc.creatorJanssen, G.C.A.M.es
dc.creatorHoy, R.es
dc.creatorHosson, J.Th.M. dees
dc.date.accessioned2023-07-03T09:33:20Z
dc.date.available2023-07-03T09:33:20Z
dc.date.issued2005-09-01
dc.identifier.citationEscobar-Galindo, R., Veen, A.v., Schut, H., Janssen, G.C.A.M., Hoy, R. y Hosson, J.T.M.d. (2005). Adhesion behaviour of CrNx coatings on pre-treated metal substrates studied in situ by PBA and ESEM after annealing. Surface and Coatings Technology, 199 (1), 57-65. https://doi.org/10.1016/j.surfcoat.2005.04.018.
dc.identifier.issn0257-8972 (impreso)es
dc.identifier.issn1879-3347 (online)es
dc.identifier.urihttps://hdl.handle.net/11441/147628
dc.description.abstractIn this paper we present the first combined Positron Beam Analysis (PBA) and Environmental Scanning Electron Microscopy (ESEM) adhesion study on thin chromium nitride (CrNx) coatings. Both techniques are combined with a 4-point bending stage. PBA monitors the creation of open volume in the ceramic/metal interface prior to delamination while ESEM observations provide a picture of the delamination process itself. By varying the positron implantation energy, the coating layer or the coating/substrate interface can be studied separately. Coatings of 500 nm thickness were deposited via a physical vapour deposition (PVD) process on different types of steel and on polycrystalline copper. Samples were studied as deposited, after 30 min annealing at 973K, and during the 4-point bending test, respectively. After annealing the PBA results have changed depending on the substrate and the treatment. The positron S parameter associated to the nitride coating increases over the whole layer for samples deposited on tool steel and polycrystalline copper. In the case of the CrNx layers deposited on interstitial free steel, there is a lower S parameter in the first 75 nm of the coating. This 2-layer structure inside the coating is more pronounced if the substrate is implanted with metal ions prior to the deposition. The positron parameter changes observed in the coatings after annealing are confirmed by ESEM observations and it is related to the structural changes in the coating. The S value ascribed to the interface increases in all samples after the annealing process confirming the creation of open volume at the interface. The 4-point bending tests revealed a plastic deformation of the coating deposited on the soft IF substrate and a brittle delamination of the film when deposited on the hard tool steel.es
dc.formatapplication/pdfes
dc.format.extent9es
dc.language.isoenges
dc.publisherScienceDirectes
dc.relation.ispartofSurface and Coatings Technology, 199 (1), 57-65.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectAdhesion behavioures
dc.subjectCrNx coatingses
dc.subjectPre-treated metal substrateses
dc.subjectPositron Beam Analysis (PBA)es
dc.subjectScanning electron microscopyes
dc.titleAdhesion behaviour of CrNx coatings on pre-treated metal substrates studied in situ by PBA and ESEM after annealinges
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Física Aplicada Ies
dc.relation.publisherversionhttps://www.sciencedirect.com/science/article/pii/S0257897205005384es
dc.identifier.doi10.1016/j.surfcoat.2005.04.018es
dc.journaltitleSurface and Coatings Technologyes
dc.publication.volumen199es
dc.publication.issue1es
dc.publication.initialPage57es
dc.publication.endPage65es

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