Artículo
Influence of the surface morphology and microstructure on the biological properties of Ti–Si–C–N–O coatings
Autor/es | Oliveira, Cristina
Escobar-Galindo, Ramón Palacio Orcajo, Carlos Vázquez, L. Espinosa, Ana Almeida, Bernardo Gonçalves Henriques, M. Calderon, V.S. Carvalho, Sandra |
Departamento | Universidad de Sevilla. Departamento de Física Aplicada I |
Fecha de publicación | 2010-08-02 |
Fecha de depósito | 2023-06-23 |
Publicado en |
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Resumen | Detailed structural, microstructural, biofilm formation and cytotoxicity studies were performed on Ti–Si–C–ON hard coatings prepared by DC reactive magnetron sputtering, in order to evaluate the relation among these ... Detailed structural, microstructural, biofilm formation and cytotoxicity studies were performed on Ti–Si–C–ON hard coatings prepared by DC reactive magnetron sputtering, in order to evaluate the relation among these properties. Compositional analysis showed the existence of two distinct regimens; regime I: high C/Si atomic ratio (C/Si ≥ 1.42) and intermediate N/Ti atomic ratio; regime II: low C/Si atomic ratio (C/Si ≤ 0.49) and low N/Ti atomic ratio. The structural analysis revealed that, in regime I, films crystallized in a B1-NaCl crystal structure typical of TiC0.2N0.8. In regime II, the decrease of C/Si and increase in silicon concentration led to the formation of Ti–Si–C–ON along with a reduction of grain size in the films. Atomic force microscopy observations showed that the surface morphology of these Ti–Si–C–ON films became smoother when the silicon content increased and the nitrogen content decreased, which is consistent with the formation of nanosized clusters. Concerning biological properties, it was observed that cytotoxicity could be related with the titanium concentration while biofilm formation ability was found to be related with the surface morphology of the films. |
Agencias financiadoras | Ministerio de Ciencia e Innovación (MICIN). España |
Identificador del proyecto | CSD2008-00023 (FUNCOAT)
HP2007-0116 |
Cita | Oliveira, C., Escobar-Galindo, R., Palacio Orcajo, C., Vázquez, L., Espinosa, A., Almeida, B.G.,...,Carvalho, S. (2010). Influence of the surface morphology and microstructure on the biological properties of Ti–Si–C–N–O coatings. Thin Solid Films, 518 (20), 5694-5699. https://doi.org/10.1016/j.tsf.2010.05.050. |
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