Artículo
Revealing the Impact of Different Iron-Based Precursors on the ‘Catalytic’ Graphitization for Synthesis of Anode Materials for Lithium Ion Batteries
Autor/es | Frankenstein, Lars
Glomb, Pascal Ramírez Rico, Joaquín Winter, Martin Placke, Tobias Gómez Martín, Aurora |
Departamento | Universidad de Sevilla. Departamento de Física de la Materia Condensada |
Fecha de publicación | 2023 |
Fecha de depósito | 2023-04-19 |
Publicado en |
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Resumen | Low cost and environmentally friendly production of graphite anodes from naturally available biomass resources is of great importance to satisfy the increasing material demand for lithium ion batteries. Herein, graphitization ... Low cost and environmentally friendly production of graphite anodes from naturally available biomass resources is of great importance to satisfy the increasing material demand for lithium ion batteries. Herein, graphitization of coffee ground was performed using four different iron-based activating additives, including iron (III) chloride, iron (III) nitrate, iron (III) oxide and pure iron, following either a wet or a dry mixing approach. The structural development regarding the type of activator used and the impact on the corresponding electrochemical performance are systematically investigated. A maximum degree of graphitization between 55 and 74 % (as determined by Raman spectroscopy) is attained using iron (III) chloride and iron powder, respectively. The graphitic anode material synthesized using iron powder reached a maximum reversible capacity of ≈320 mAh g−1 at a rate of 0.1 C. This study provides significant insights into the impact of activators on the design of synthetic graphite from renewable sources. |
Agencias financiadoras | Ministry of Economic Affairs, Innovation, Digitalization and Energy of the State of North Rhine-Westphalia (MWIDE) Junta de Andalucía Ministerio de Ciencia e Innovación (MICIN). España |
Identificador del proyecto | 313-W044A
P20-01186 US-1380856 PID2019-107019RB-I00 |
Cita | Frankenstein, L., Glomb, P., Ramírez Rico, J., Winter, M., Placke, T. y Gómez Martín, A. (2023). Revealing the Impact of Different Iron-Based Precursors on the ‘Catalytic’ Graphitization for Synthesis of Anode Materials for Lithium Ion Batteries. ChemElectroChem, 10 (5), e202201073. https://doi.org/10.1002/celc.202201073. |
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