Ver ítem 

Mostrar el registro sencillo del ítem

Artículo

Opened Access
Electrolytic synthesis of chloroacetic acids in a filter-press reactor from polychloromethanes

dc.creatorOlloqui Sariego, José Luises
dc.creatorMolina Romo, Víctor Manueles
dc.creatorGonzález Arjona, Domingoes
dc.creatorRoldán González, Emilioes
dc.creatorDomínguez Pérez, Manuel Maríaes
dc.date.accessioned2022-03-24T10:04:38Z
dc.date.available2022-03-24T10:04:38Z
dc.date.issued2010
dc.identifier.citationOlloqui Sariego, J.L., Molina Romo, V.M., González Arjona, D., Roldán González, E. y Domínguez Pérez, M.M. (2010). Electrolytic synthesis of chloroacetic acids in a filter-press reactor from polychloromethanes. Electrochemistry Communications, 12 (7), 952-954.
dc.identifier.issn1388-2481es
dc.identifier.urihttps://hdl.handle.net/11441/131246
dc.description.abstractElectrochemical carboxylation of carbon tetrachloride and chloroform to synthesize chloroacetic acids in mild conditions has been investigated by galvanostatic electrolyses using a homemade electrochemical filter-press reactor. Undivided filter-press reactor consisting of a planar Zn cathode and a planar Al sacrificial anode has been shown to be an optimal electrochemical device for the electrocarboxylation reaction. The influence of some operative parameters, such as current density and concentration of supporting electrolyte, on the efficiency and selectivity of the synthetic process has been investigated. Highly current efficiencies and target products yields (both of them > 85%) were achieved in all cases, whereas byproducts formation was minimal.es
dc.description.sponsorshipDirección General de Ciencia y Tecnología de España. CTQ2004-00362es
dc.formatapplication/pdfes
dc.format.extent3 p.es
dc.language.isoenges
dc.publisherElsevieres
dc.relation.ispartofElectrochemistry Communications, 12 (7), 952-954.
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional*
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectPolychloromethaneses
dc.subjectChloroacetic acidses
dc.subjectElectrochemical carboxylationes
dc.subjectFilter-press reactores
dc.subjectSacrificial anodeses
dc.titleElectrolytic synthesis of chloroacetic acids in a filter-press reactor from polychloromethaneses
dc.typeinfo:eu-repo/semantics/articlees
dcterms.identifierhttps://ror.org/03yxnpp24
dc.type.versioninfo:eu-repo/semantics/publishedVersiones
dc.rights.accessRightsinfo:eu-repo/semantics/openAccesses
dc.contributor.affiliationUniversidad de Sevilla. Departamento de Química Físicaes
dc.relation.projectIDCTQ2004-00362es
dc.relation.publisherversionhttps://doi.org/10.1016/j.elecom.2010.04.030es
dc.identifier.doi10.1016/j.elecom.2010.04.030es
dc.journaltitleElectrochemistry Communicationses
dc.publication.volumen12es
dc.publication.issue7es
dc.publication.initialPage952es
dc.publication.endPage954es
dc.identifier.sisius6519961es
dc.contributor.funderDirección General de Ciencia y Tecnología. Españaes

FicherosTamañoFormatoVerDescripción
1-s2.0-S1388248110001852-main.pdf178.8KbIcon   [PDF] Ver/Abrir  

Este registro aparece en las siguientes colecciones

Mostrar el registro sencillo del ítem

Attribution-NonCommercial-NoDerivatives 4.0 Internacional
Excepto si se señala otra cosa, la licencia del ítem se describe como: Attribution-NonCommercial-NoDerivatives 4.0 Internacional