dc.creator | Escobar-Galindo, Ramón | es |
dc.creator | Heras Pérez, Irene | es |
dc.creator | Guillén Rodríguez, Elena | es |
dc.creator | Munnik, Frans | es |
dc.creator | Azkona, Ibon | es |
dc.creator | Krause, Matthias | es |
dc.date.accessioned | 2021-12-02T08:13:53Z | |
dc.date.available | 2021-12-02T08:13:53Z | |
dc.date.issued | 2021-09 | |
dc.identifier.citation | Escobar-Galindo, R., Heras Pérez, I., Guillén Rodríguez, E., Munnik, F., Azkona, I. y Krause, M. (2021). Comprehensive microstructural and optical characterization of the thermal stability of aluminum‑titanium oxynitride thin films after high temperature annealing in air. Emergent Materials, 5 | |
dc.identifier.issn | 2522-5731 | es |
dc.identifier.issn | 2522-574X | es |
dc.identifier.uri | https://hdl.handle.net/11441/127925 | |
dc.description.abstract | The thermal stability of two AlyTi1-
y(OxN1-x) layers prepared by cathodic vacuum arc deposition with different oxygen content
was studied after high temperature annealing of the samples in air. These layers were designed to be part of solar-selective
coating (SSC) stacks. Compositional and microstructural characterization of the thin films was performed before and after the
thermal treatment by elastic recoil detection (ERD), transmission electron microscopy, and Raman spectroscopy. AlyTi1-
yN
sample was stable after 2 h of annealing at 450 °C. Initial stages of the formation of a surface oxide layer after annealing at
650 °C were observed both by ERD and Raman analysis. Contrarily, no changes were found after 2 h annealing treatment
either at 450 and 650 °C in the composition and microstructure of AlyTi1-
y(OxN1-x) sample. In both samples, the formation
of a surface anatase TiO2
film was reported after 2 h annealing at 800 °C. These compositional and microstructural changes
were correlated with the optical properties determined by spectroscopic ellipsometry. A transition from metallic to dielectric
behavior with increasing annealing temperature was observed. These results complete the durability studies on the designed
SSC based on AlyTi1-
y(OxN1-x) materials, confirming that these stacks withstand breakdown at 600 °C in air. | es |
dc.description.sponsorship | H2020 RISE project “Framework of Innovation for Engineering of New Durable Solar Surfaces GA-645725 | es |
dc.description.sponsorship | Spanish Ministry of Science and Innovation project “Recubrimientos innovadores preparados por magnetron sputtering para absorción solar selectiva" PID2019-104256RB-I00 | es |
dc.description.sponsorship | Agencia Estatal de Investigacion (AEI) project “Entrenamiento avanzado en materiales para superficies solares duraderas EIN2020-112163 /AEI/10.13039/501100011033 | es |
dc.format | application/pdf | es |
dc.format.extent | 10 p. | es |
dc.language.iso | eng | es |
dc.publisher | Springer | es |
dc.relation.ispartof | Emergent Materials, 5 | |
dc.rights | Attribution-NonCommercial-NoDerivatives 4.0 Internacional | * |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.title | Comprehensive microstructural and optical characterization of the thermal stability of aluminum‑titanium oxynitride thin films after high temperature annealing in air | es |
dc.type | info:eu-repo/semantics/article | es |
dcterms.identifier | https://ror.org/03yxnpp24 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | es |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | es |
dc.contributor.affiliation | Universidad de Sevilla. Departamento de Física Aplicada I | es |
dc.relation.publisherversion | https://link.springer.com/article/10.1007%2Fs42247-021-00298-z | es |
dc.identifier.doi | 10.1007/s42247-021-00298-z | es |
dc.contributor.group | Universidad de Sevilla. TEP-946 Materiales y Nanotecnología para la Innovación | es |
dc.journaltitle | Emergent Materials | es |
dc.publication.issue | 5 | es |