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Article
Characterization of mechanosynthesized Bi1−xSmxFeO3 samples unencumbered by secondary phases or compositional inhomogeneity
(Elsevier, 2017)
High-quality samples, in terms of phase purity and dielectric properties, of composition Bi1−xSmxFeO3 (0.05 ≤ x ≤ 0.20) have for the first time been prepared by mechanosynthesis. Close inspection of the powder diffraction ...
Article
Pyrolysis kinetics of ethylene-propylene (EPM) and ethylene-propylene-diene (EPDM)
(Elsevier, 2013)
The thermal degradation kinetics of several ethylene-propylene copolymers (EPM) and ethylene-propylene-diene terpolymers (EPDM), with different chemical compositions, have been studied by means of the combined kinetic ...
Article
Article
New insights on the kinetic analysis of isothermal data: The independence of the activation energy from the assumed kinetic model
(American Chemical Society, 2015)
Isothermal experiments are widely employed to study the kinetics of solid-state reactions or processes to extract essential kinetic information needed for modeling the processes at an industrial scale. The kinetic analysis ...
Article
Hallmarks of mechanochemistry: From nanoparticles to technology
(Royal Society of Chemistry (Great Britain), 2013)
The aim of this review article on recent developments of mechanochemistry (nowadays established as a part of chemistry) is to provide a comprehensive overview of advances achieved in the field of atomistic processes, phase ...
Article
Generalized master plots as a straightforward approach for determining the kinetic model: The case of cellulose pyrolysis
(Elsevier, 2013)
The thermal degradation of cellulose is a complex reaction and, despite the large amount of work by many investigators during the last decades, the actual understanding of the thermal decomposition kinetics is still very ...
Article
Clarifications regarding the use of model-fitting methods of kinetic analysis for determining the activation energy from a single non-isothermal curve
(Chemistry Central, 2013)
Abstract Background This paper provides some clarifications regarding the use of model-fitting methods of kinetic analysis for estimating the activation energy of a process, in response to some results recently published ...
Article
Influencia de la adición de estaño en el proceso de precipitación en una aleación de Cu-Ni-Zn
(Consejo Superior de Investigaciones Científicas, 2016)
Mediante calorimetría diferencial de barrido (DSC), medidas de microdureza y microscopía electrónica de transmisión de alta resolución (HRTEM) se estudió la influencia de la adición de 1,1% en peso de estaño en el ...
Article
Magnesium hydride for energy storage applications: The kinetics of dehydrogenation under different working conditions
(Elsevier, 2016)
A new approach to the kinetics of magnesium hydride dehydrogenation is considered. A model able to predict the dehydrogenation under different experimental conditions has been proposed. A new combined kinetic analysis ...
Article
Scission kinetic model for the prediction of polymer pyrolysis curves from chain structure
(Elsevier, 2014)
There is a significant interest in correlating polymer structure with thermal degradation behavior. Thus, polymer pyrolysis curves could be predicted from the chemical structure of the polymer. Recent proposals correlate ...