Buscar
Mostrando ítems 1-2 de 2
Artículo
Aluminium(iii) dialkyl 2,6-bisimino-4R-dihydropyridinates(−1): selective synthesis, structure and controlled dimerization
(Royal Society of Chemistry, 2019)
A family of stable and otherwise selectively unachievable 2,6-bisimino-4-R-1,4-dihydropyridinate aluminium (III) dialkyl complexes [AlR’2(4-R-i PrBIPH)] (R = Bn, Allyl; R’ = Me, Et, i Bu) have been synthesized, taking ...
Artículo
Neutral Bis(imino)-1,4-dihydropyridinate and Cationic Bis(imino)pyridine σ-Alkylzinc(II) Complexes as Hydride Exchange Systems: Classic Organometallic Chemistry Meets Ligand-Centered, Biomimetic Reactivity
(American Chemical Society, 2018)
The 1,4-dihydropyridinate complex [(4-BnHBIP)Zn(Bn)], readily available through the highly selective reaction of a 2,6-bis(imino)pyridine ligand with dibenzylzinc, contains two distinct reactive centers. One of them is ...