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Artículo
Theoretical Analysis of Polynuclear Zinc Complexes Isolobally Related to Hydrocarbons
(MDPI, 2022)
Based on the isolobal analogy of ZnCp (Cp = η5-C5H5) and ZnR (R = alkyl or aryl group) fragments with hydrogen atom and fragment [Zn(CO)2] with a CH2 carbene, the following complexes [(ZnCp)2{µ-Zn(CO)2}], 1, [(ZnPh)2{µ-Zn(CO)2}], ...
Artículo
New Phosphonite Ligands with High Steric Demand and Low Basicity: Synthesis, Structural Properties and Cyclometalated Complexes of Pt(II)
(Multidisciplinary Digital Publishing Institute (MDPI), 2022)
Two phosphonite ligands bearing the highly sterically demanding 2,6-bis (2,6-dimethylphenyl)phenyl group (ArXyl2), PArXyl2(OPhNO2)2 and PArXyl2(OPhNO2)2, were prepared from the parent dihalophosphines PArXyl2X2 (X = Cl, ...