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Artículo
Large-scale high-temperature solar energy storage using natural minerals
(Elsevier, 2017)
The present work is focused on thermochemical energy storage (TCES) in Concentrated Solar Power (CSP) plants by means of the Calcium-Looping (CaL) process using cheap, abundant and non-toxic natural carbonate minerals. CaL ...
Artículo
Influence of gold particle size in Au/C catalysts for base-free oxidation of glucose
(Elsevier, 2017)
A series of gold colloids were prepared and immobilized on commercial activated carbon. The influence of the colloid preparation and stability were studied and related to the gold particle size in the final catalyst. The ...
Artículo
Characterization of mechanosynthesized Bi1−xSmxFeO3 samples unencumbered by secondary phases or compositional inhomogeneity
(Elsevier, 2017)
High-quality samples, in terms of phase purity and dielectric properties, of composition Bi1−xSmxFeO3 (0.05 ≤ x ≤ 0.20) have for the first time been prepared by mechanosynthesis. Close inspection of the powder diffraction ...
Artículo
Functionalization of 3-Iridacyclopentenes
(Wiley, 2017)
Members of a series of iridacyclopentenes of composition [TpMe2Ir(k2-C,C-CH2CR′=CRCH2)(CO)] (TpMe2=hydrotris(3,5-dimethylpyrazolyl)borate; R=R′=H, 1; R=Me, R′=H, 2; R=R′=Me, 3) have been subjected to common organic chemistry ...
Artículo
Rhodium(I) Complexes with Ligands Based on N-Heterocyclic Carbene and Hemilabile Pyridine Donors as Highly E Stereoselective Alkyne Hydrosilylation Catalysts
(American Chemical Society, 2017)
Cationic rhodium(I) complexes containing picolyl-NHC (NHC = N-heterocyclic carbene) ligands that differ in the substitution at the 6-position of the pyridine donor serve as efficient E-selective alkyne hydrosilylation ...
Artículo
Large-Scale Storage of Concentrated Solar Power from Industrial Waste
(American Chemical Society, 2017)
Deep penetration of renewable energies into the grid relies on the development of large-scale energy storage technologies using cheap, abundant, and nontoxic materials. Concentrated solar power (CSP) is particularly suitable ...
Artículo
Understanding the differences in catalytic performance for hydrogen production of Ni and Co supported on mesoporous SBA-15
(Elsevier, 2017)
Three mono and bimetallic Nix Co1−x /SBA-15 catalysts (x = 1, 0.5 and 0) with a total metallic content of 10 wt% have been prepared by a deposition–precipitation (DP) method. The catalytic performances on the dry reforming ...
Artículo
Preparation of ytterbium substituted BiFeO3 multiferroics by mechanical activation
(Elsevier, 2017)
Samples in the system Bi1−xYbxFeO3 (0.02 ≤ × ≤ 0.07) have for the first time been prepared by mechanical activation followed by sintering. XRD and DSC measurements show that the solubility limit of ytterbium in the R3c ...
Artículo
Effect of the crystal chemistry on the hydration mechanism of swelling micas
(Elsevier, 2017)
Swelling and dehydration under minor changes in temperature and water vapor pressure is an important property that clays and clay minerals exhibit. In particular, their interlayer space, the solid-water interface and the ...