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Artículo
Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs
(American Chemical Society, 2020)
Introducing transition metals into frustrated Lewis pair systems has attracted considerable attention in recent years. Here we report a selection of three metal-only frustrated systems based on Au(I)/Pt(0) combinations and ...
Artículo
Synthesis and Photophysical Properties of Au(III)-Ag(I) Aggregates
(American Chemical Society, 2019)
Cyclometalated gold(III) complexes of the type (CNC)AuX [HCNCH = 2,6-bis(4-ButC6H4)pyrazine; 2,6-bis(4-ButC6H4)pyridine, or 2,6-bis(4-ButC6H4)4-Butpyridine; X = CN, CH(COMe)2, or CH(CN)2] have been used as building blocks ...
Artículo
Confining Iron Oxide Nanocubes inside Submicrometric Cavities as a Key Strategy to Preserve Magnetic Heat Losses in an Intracellular Environment
(American Chemical Society, 2019-11-19)
The design of magnetic nanostructures whose magnetic heating efficiency remains unaffected at the tumor site is a fundamental requirement to further advance magnetic hyperthermia in the clinic. This work demonstrates that ...
Artículo
Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems
(Wiley-Blackwell, 2020)
A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) metal-only frustrated Lewis pair (FLP) is described herein. The drastic effects on H2 activation derived ...
Artículo
Metal-only Lewis Pairs of Rhodium with s, p and d-Block Metals
(Wiley, 2020)
Metal-only Lewis pairs (MOLPs) in which the two metal fragments are solely connected by a dative M→M bond represent privileged architectures to acquire fundamental understanding of bimetallic bonding. This has important ...