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Artículo
Supported σ-Complexes of Li−C Bonds from Coordination of Monomeric Molecules of LiCH3, LiCH2CH3 and LiC6H5 to Mo≣Mo Bonds
(German Chemical Society, 2022)
LiCH3 and LiCH2CH3 react with the complex [Mo2(H)2(μ-AdDipp2)2(thf)2] (1⋅thf) with coordination of two molecules of LiCH2R (R=H, CH3) and formation of complexes [Mo2{μ-HLi(thf)CH2R}2(AdDipp2)2], 5⋅LiCH3 and 5⋅LiCH2CH3, ...
Artículo
Dialkylterphenyl Phosphine-Based Palladium Precatalysts for Efficient Aryl Amination of N-Nucleophiles
(Wiley-Blackwell, 2020)
A series of 2-aminobiphenyl palladacycles supported by dialkylterphenyl phosphines, PR2Ar′ (R=Me, Et, iPr, Cyp (cyclopentyl), Ar′=ArDipp2, ArXyl2f, Dipp (2,6-C6H3-(2,6-C6H3-(CHMe2)2)2), Xyl=xylyl) have been prepared and ...
Artículo
Ni(II) Precatalysts Enable Thioetherification of (Hetero)Aryl Halides and Tosylates and Tandem C−S/C−N Couplings
(Wiley-Blackwell, 2021)
Ni-catalyzed C−S cross-coupling reactions have received less attention compared with other C-heteroatom couplings. Most reported examples comprise the thioetherification of most reactive aryl iodides with aromatic thiols. ...
Artículo
Catalytic Converters for Vehicle Exhaust: Fundamental Aspects and Technology Overview for Newcomers to the Field
(MDPI, 2021-06)
This works aims to provide an understanding on basic chemical kinetics pertaining to three-way catalytic (TWC) converters from an educational perspective, aimed at those novel readers in this field. Rate of reactions and ...
Artículo
Catalytic performance of cobalt supported onto APTES functionalized TiO2 for Fischer-Tropsch reaction
(Science, 2023)
Cobalt supported TiO2 catalysts have been prepared by wet-impregnation and by immobilization over APTES (3-aminopropyl triethoxysilane) grafted TiO2. Impregnated system showed better catalytic performance after reduction ...
Artículo
Recent advances in selective oxidation of biomass-derived platform chemicals over gold catalysts
(Elsevier, 2020)
Gold is without a doubt the best known metal for chemical oxidation. The noblest of the noble metals gained its place because of its resistance to overoxidation, low temperature of operation, especially in gas-phase ...
Artículo
Flexible NiRu Systems for CO2 Methanation: From Efficient Catalysts to Advanced Dual-Function Materials
(Multidisciplinary Digital Publishing Institute (MDPI), 2023)
CO2 emissions in the atmosphere have been increasing rapidly in recent years, causing global warming. CO2 methanation reaction is deemed to be a way to combat these emissions by converting CO2 into synthetic natural gas, ...
Artículo
Are Ni/ and Ni5Fe1/biochar catalysts suitable for synthetic natural gas production? A comparison with γ-Al2O3 supported catalysts
(KeAi Communications Co., 2021)
Among challenges implicit in the transition to the post–fossil fuel energetic model, the finite amount of resources available for the technological implementation of CO2 revalorizing processes arises as a central issue. ...
Artículo
Electrocatalytic CO2 conversion to C2 products: catalysts design, market perspectives and techno-economic aspects
(Elsevier, 2022)
The energy crisis caused by the incessant growth in global energy demand joint to its associated greenhouse emissions motivates the urgent need to control and mitigate atmospheric CO2 levels. Leveraging CO2 as carbon pool ...
Artículo
Reversible carbon-boron bond formation at platinum centers through σ-BH complexes
(Royal Society of Chemistry, 2021)
A reversible carbon–boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, Pt(II) complex [Pt(ItBuiPr′)(ItBuiPr)][BArF], 1, with tricoordinated boranes HBR2. X-ray diffraction ...