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Structural diversity and magnetic properties of copper(ii) quinaldinate compounds with amino alcohols
(Royal Society of Chemistry, 2022)
The reactions between [Cu(quin)2(H2O)] (quin− = the anionic form of quinoline-2-carboxylic acid) and a series of aliphatic amino alcohols have yielded structurally very diverse copper(II) complexes, labelled a–g. Single-crystal ...
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Elucidation of water promoter effect of proton conductor in wgs reaction over pt-based catalyst: An operando drifts study
(Multidisciplinary Digital Publishing Institute (MDPI), 2020)
A conventional Pt/CeO2/Al2O3 catalyst physically mixed with an ionic conductor (Mo-or Eu-doped ZrO2) was tested at high space velocity (20,000 h−1 and 80 L h−1 gcat−1) under model conditions (only with CO and H2O) and ...
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Effect of Basicity on the Hydrolysis of the Bi(III) Aqua Ion in Solution: An Ab Initio Molecular Dynamics Study
(American Chemical Society, 2018-02-22)
Hydrolysis of the Bi(III) aqua ion under a range of solution conditions has been studied by means of ab initio molecular dynamics simulations. While the Bi(III) aqua ion is stable in pure water, there is an increasing ...
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Tailoring the Band Gap in the ZnS/ZnSe System: Solid Solutions by a Mechanically Induced Self-Sustaining Reaction
(American Chemical Society, 2019)
The complete ZnSxSe1−x solid solution was successfully obtained by the mechanochemical process denoted as a mechanically induced self-sustaining reaction. Excellent control of the chemical stoichiometry of the solid ...
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New 3D Printing Strategy for Structured Carbon Devices Fabrication
(MDPI, 2023)
This work shows a new method for the preparation of 100% carbon-structured devices. The method is based on resorcinol-formaldehyde polymerization, using starch as a binder with the addition of a certain amount of external ...
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Large-scale high-temperature solar energy storage using natural minerals
(Elsevier, 2017)
The present work is focused on thermochemical energy storage (TCES) in Concentrated Solar Power (CSP) plants by means of the Calcium-Looping (CaL) process using cheap, abundant and non-toxic natural carbonate minerals. CaL ...
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Spinel Ferrite Catalysts for CO2 Reduction Via Reverse Water Gas Shift Reaction
(Elsevier, 2023)
The production of CO via Reverse Water Gas Shift (RWGS) reaction is a suitable route for CO2 valorization. In this study a series of modified spinels AB2O4 (A site = Ni, Zn and Cu and B site=Fe) are investigated as RWGS ...
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Microwave-assisted synthesis of biocompatible europium-doped calcium hydroxyapatite and fluoroapatite luminescent nanospindles functionalized with poly(acrylic acid)
(American Chemical Society, 2013-02-12)
Europium-doped calcium hydroxyapatite and fluoroapatite nanophosphors functionalized with poly(acrylic acid) (PAA) have been synthesized through a one-pot microwave-assisted hydrothermal method from aqueous basic solutions ...
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Versatile Ni-Ru catalysts for gas phase CO2 conversion: Bringing closer dry reforming, reverse water gas shift and methanation to enable end-products flexibility
(Elsevier, 2022)
Advanced catalytic materials able to catalyse more than one reaction efficiently are needed within the CO2 utilisation schemes to benefit from end-products flexibility. In this study, the combination of Ni and Ru (15 and ...
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Revealing the substitution mechanism in Eu3+:CaMoO4 and Eu3+,Na+:CaMoO4 phosphors
(Royal Society of Chemistry, 2018)
Eu3+-Doped calcium molybdate is an excellent phosphor for lighting and display devices due to the very intense pure red emission after UV excitation. It has been reported in the literature that the CaMoO4 unit cell volume ...