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Large-scale high-temperature solar energy storage using natural minerals
(Elsevier, 2017)
The present work is focused on thermochemical energy storage (TCES) in Concentrated Solar Power (CSP) plants by means of the Calcium-Looping (CaL) process using cheap, abundant and non-toxic natural carbonate minerals. CaL ...
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Nanoclay nucleation effect in the thermal stabilization of a polymer nanocomposite: A kinetic mechanism change
(American Chemical Society, 2012)
The enhanced thermal stability of polymer-clay nanocomposites over the original polymers is one of their most interesting features, and it has been profusely studied within the last decades. Here, a thorough kinetic analysis ...
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Characterization of mechanosynthesized Bi1−xSmxFeO3 samples unencumbered by secondary phases or compositional inhomogeneity
(Elsevier, 2017)
High-quality samples, in terms of phase purity and dielectric properties, of composition Bi1−xSmxFeO3 (0.05 ≤ x ≤ 0.20) have for the first time been prepared by mechanosynthesis. Close inspection of the powder diffraction ...
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Pressure Effect on the Multicycle Activity of Natural Carbonates and a Ca/Zr Composite for Energy Storage of Concentrated Solar Power
(American Chemical Society, 2018)
This work is focused on the use of the Calcium-Looping process (CaL) in Concentrated Solar Power (CSP) plants for Thermochemical Energy Storage (TCES). Cheap, abundant and nontoxic natural carbonate minerals, such as ...
Artículo
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Phase-pure BiFeO3 produced by reaction flash-sintering of Bi2O3 and Fe2O3
(Royal Society of Chemistry, 2018)
Mixed powders of Bi2O3 and Fe2O3 are shown to yield single-phase, dense nanostructured polycrystals of BiFeO3 in reaction flash sintering experiments, carried out by applying a field of 50 V cm 1 and with the current ...
Artículo
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High-performance and low-cost macroporous calcium oxide based materials for thermochemical energy storage in concentrated solar power plants
(Elsevier, 2019)
High energy density, cycling stability, low cost and scalability are the main features required for thermochemical energy storage systems to achieve a feasible integration in Concentrating Solar Power plants (CSP). While ...
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Influence of ball milling on CaO crystal growth during limestone and dolomite calcination: Effect on CO2 capture at Calcium Looping conditions
(American Chemical Society, 2016)
The multicycle CO2 capture performance of CaO derived from the calcination of ball-milled limestone and dolomite have been tested under high temperature and high CO2 concentration environment for the first time. Here it ...
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Relevant influence of limestone crystallinity on CO2 capture in the Ca-looping technology at realistic calcination conditions
(American Chemical Society, 2014)
We analyze the role of limestone crystallinity on its CO2 capture performance when subjected to carbonation/calcination cycles at conditions mimicking the Ca-looping (CaL) technology for postcombustion CO 2 capture. The ...
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Limestone calcination nearby equilibrium: Kinetics, CaO crystal structure, sintering and reactivity
(American Chemical Society, 2015)
In this work, we analyze limestone calcination kinetics at environmental conditions involving a CO2 partial pressure P close to the equilibrium pressure Peq by means of in situ X-ray diffraction (XRD) and thermogravimetric ...
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Effect of heat pretreatment/recarbonation in the Ca-looping process at realistic calcination conditions
(American Chemical Society, 2014)
Even though an increasing number of pilot-scale plants are demonstrating the potential efficiency of the Ca-looping technology to capture CO2 at a commercial level, a still standing matter of concern is the loss of carbonation ...