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Artículo
New 3D Printing Strategy for Structured Carbon Devices Fabrication
(MDPI, 2023)
This work shows a new method for the preparation of 100% carbon-structured devices. The method is based on resorcinol-formaldehyde polymerization, using starch as a binder with the addition of a certain amount of external ...
Artículo
Broad-Scope Amination of Aryl Sulfamates Catalyzed by a Palladium Phosphine Complex
(American Chemical Society, 2023-08-03)
Among phenol-derived electrophiles, aryl sulfamates are attractive substrates since they can be employed as directing groups for C–H functionalization prior to catalysis. However, their use in C–N coupling is limited only ...
Artículo
Organometallic Nanoparticles Ligated by NHCs: Synthesis, Surface Chemistry and Ligand Effects
(MDPI, 2020)
Over the last 20 years, the use of metallic nanoparticles (MNPs) in catalysis has awakened a great interest in the scientific community, mainly due to the many advantages of this kind of nanostructures in catalytic ...
Artículo
Ammonia–Borane Dehydrogenation Catalyzed by Dual-Mode Proton-Responsive Ir-CNNH Complexes
(American Chemical Society, 2021)
Metal complexes incorporating proton-responsive ligands have been proved to be superior catalysts in reactions involving the H2 molecule. In this contribution, a series of IrIII complexes based on lutidine-derived CNNH ...
Artículo
Electrophilic activation of alkynes promoted by a cationic alkylidene complex of Pt(II)
(Royal Society of Chemistry, 2022-03-18)
Pt(II) alkylidene 1a has been reacted with terminal alkynes to afford ylide complexes 3a-d, resulting from electrophilic activation of the C≡C bond and its insertion into the platinacyclic fragment of 1a that contains the ...
Artículo
Reduction of N2O with hydrosilanes catalysed by RuSNS nanoparticles
(Royal Society of Chemistry, 2022)
A series of RuSNS nanoparticles, prepared by decomposition of Ru(COD)(COT) with H2 in the presence of an SNS ligand, have been found to catalyse the reduction of the greenhouse gas N2O to N2 employing different hydrosilanes.
Artículo
Nucleophilic Nickel and Palladium Pincer Hydroxides: A Study of Their Reactions with Dimethyl Carbonate and Other Non-Alkylating Organic Electrophiles
(Wiley-Blackwell, 2021)
The reactions of the pincer hydroxide complexes [(iPrPCP)M(OH)] (M=Ni, Pd) with dimethyl carbonate (DMC), and a set of organic electrophiles including benzaldehyde have been investigated in the context of our ongoing ...
Artículo
Alkane Metathesis over Immobilized Pincer-ligated Iridium Complexes: Effect of Support Nature
(Elsevier, 2023)
In this work, catalytic alkane metathesis has been evaluated as a suitable approach to upcycle hydrocarbons (polyolefins) at moderate temperatures. To this end, a pincer-ligated iridium complex (dehydrogenation catalyst) ...