Buscar
Mostrando ítems 1-3 de 3
Artículo
Broad-Scope Amination of Aryl Sulfamates Catalyzed by a Palladium Phosphine Complex
(American Chemical Society, 2023-08-03)
Among phenol-derived electrophiles, aryl sulfamates are attractive substrates since they can be employed as directing groups for C–H functionalization prior to catalysis. However, their use in C–N coupling is limited only ...
Artículo
Ammonia–Borane Dehydrogenation Catalyzed by Dual-Mode Proton-Responsive Ir-CNNH Complexes
(American Chemical Society, 2021)
Metal complexes incorporating proton-responsive ligands have been proved to be superior catalysts in reactions involving the H2 molecule. In this contribution, a series of IrIII complexes based on lutidine-derived CNNH ...
Artículo
Electrophilic activation of alkynes promoted by a cationic alkylidene complex of Pt(II)
(Royal Society of Chemistry, 2022-03-18)
Pt(II) alkylidene 1a has been reacted with terminal alkynes to afford ylide complexes 3a-d, resulting from electrophilic activation of the C≡C bond and its insertion into the platinacyclic fragment of 1a that contains the ...