Listar Química Inorgánica por agencia financiadora "European Research Council (ERC)"
Mostrando ítems 1-18 de 18
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A dicoordinate gold(i)–ethylene complex
(Royal Society of Chemistry, 2021)The use of the exceptionally bulky tris-2-(4,40 -di-tert-butylbiphenylyl) phosphine ligand allows the isolation and ...
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Confining Iron Oxide Nanocubes inside Submicrometric Cavities as a Key Strategy to Preserve Magnetic Heat Losses in an Intracellular Environment
(American Chemical Society, 2019-11-19)The design of magnetic nanostructures whose magnetic heating efficiency remains unaffected at the tumor site is a fundamental ...
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Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag(i) metal-only Lewis pair
(Royal Society of Chemistry, 2019)Metal-only Lewis pairs made of Pt(0)/Ag(I) combinations have been previously reported, but their cooperative reactivity ...
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Dehydrogenative Double C−H Bond Activation in a Germylene-Rhodium Complex
(Wiley, 2021)Transition metal tetrylene complexes offer great opportunities for molecular cooperation due to the ambiphilic character ...
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Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study
(Wiley, 2022)The organometallic chemistry of 4d and 5d transition metals has been vastly dominated by closed-shell states. The reactivity ...
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Evidence for Genuine Bimetallic Frustrated Lewis Pair Activation of Dihydrogen with Gold(I)/Platinum(0) Systems
(Wiley-Blackwell, 2020)A joint experimental/computational effort to elucidate the mechanism of dihydrogen activation by a gold(I)/platinum(0) ...
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Metal-only Lewis Pairs of Rhodium with s, p and d-Block Metals
(Wiley, 2020)Metal-only Lewis pairs (MOLPs) in which the two metal fragments are solely connected by a dative M→M bond represent ...
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Polarized Au(i)/Rh(i) Bimetallic Pairs Cooperatively Trigger Ligand Non-innocence and Bond Activation
(Royal Society of Chemistry, 2023)The combination of molecular metallic fragments of contrasting Lewis character offers many possibilities for cooperative ...
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Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity
(American Chemical Society, 2021)Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi ...
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Revealing the substitution mechanism in Eu3+:CaMoO4 and Eu3+,Na+:CaMoO4 phosphors
(Royal Society of Chemistry, 2018)Eu3+-Doped calcium molybdate is an excellent phosphor for lighting and display devices due to the very intense pure red ...
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Reversible Hydride Migration from C5Me5 to RhI Revealed by a Cooperative Bimetallic Approach
(Wiley, 2020)The use of cyclopentadienyl ligands in organome-tallic chemistry and catalysis is ubiquitous, mostly due to theirrobust ...
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Small molecule activation with bimetallic systems: a landscape of cooperative reactivity
(Royal Society of Chemistry, 2022-09-06)There is growing interest in the design of bimetallic cooperative complexes, which have emerged due to their potential for ...
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Structural Snapshots of π-Arene Bonding in a Gold Germylene Cation
(Wiley, 2020)Heavier group 14 element cations exhibit a remarkable reactivity that has typically hampered their isolation. For the few ...
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Synthesis and Photophysical Properties of Au(III)-Ag(I) Aggregates
(American Chemical Society, 2019)Cyclometalated gold(III) complexes of the type (CNC)AuX [HCNCH = 2,6-bis(4-ButC6H4)pyrazine; 2,6-bis(4-ButC6H4)pyridine, ...
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Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs
(American Chemical Society, 2020)Introducing transition metals into frustrated Lewis pair systems has attracted considerable attention in recent years. ...
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Tuning the Inorganic Core of a reduced Ni2Ge2 Cluster
(Wiley, 2024-04)Tetranuclear cores (M−E)2 of transition metals (M) and tetrylenes (EII=Si, Ge, Sn) are key motifs in homogeneous and ...
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Unmasking the constitution and bonding of the proposed lithium nickelate “Li3NiPh3(solv)3”: revealing the hidden C6H4 ligand
(Royal Society of Chemistry, 2022)More than four decades ago, a complex identified as the planar homoleptic lithium nickelate “Li3NiPh3(solv)3” was reported ...
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Unveiling the Latent Reactivity of Cp* Ligands (C5Me5-) toward Carbon Nucleophiles on an Iridium Complex
(American Chemical Society, 2023)The divergent reactivity of the cationic iridium complex [(η5-C5Me5)IrCl(PMe2ArDipp2)]+ (ArDipp2 = C6H3-2,6-(C6H3-2,6-iPr2)2) ...