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Artículo
Electrolytic synthesis of chloroacetic acids in a filter-press reactor from polychloromethanes
(Elsevier, 2010)
Electrochemical carboxylation of carbon tetrachloride and chloroform to synthesize chloroacetic acids in mild conditions has been investigated by galvanostatic electrolyses using a homemade electrochemical filter-press ...
Artículo
Solving the Hydration Structure of the Heaviest Actinide Aqua IonKnown: The Californium(III) Case
(Wiley-Blackwell, 2010)
Wish they all could be californium: X-ray absorption spectroscopy (black points) and Monte Carlo simulations (blue line) of Cf" in aqueous solutions have been combined to determine the ligand distance and coordination ...
Artículo
Microheterogeneous catalysis
(MDPI, 2010)
The catalytic effect of micelles, polymers (such as DNA, polypeptides) and nanoparticles, saturable receptors (cyclodextrins and calixarenes) and more complex systems (mixing some of the above mentioned catalysts) have ...
Artículo
Microscopic origins of the ferromagnetic exchange coupling in oxoverdazyl-based Cu(II) complex
(American Institute of Physics Publising LLC, 2010)
The exchange channels governing the experimentally reported coupling constant Jexpt=6 cm−1 value in the verdazyl-ligand based Cu II complex Cu hfac 2 imvdz are inspected using wave function-based difference dedicated ...
Artículo
A theoretical insight into the catalytic effect of a mixed-metal oxide at the nanometer level: The case of the highly active metal/CeOx/TiO2(110) catalysts
(AIP Publishing, 2010-03)
The structural and electronic properties of CeOx species supported on the rutile TiO2 110 surface have been examined by means of periodic density-functional calculations that use a generalized gradient approximation ...
Artículo
Molecular solids of actinide hexacyanoferrate: Structure and bonding
(IOP Publishing, 2010)
The hexacyanometallate family is well known in transition metal chemistry because the remarkable electronic delocalization along the metal-cyano-metal bond can be tuned in order to design systems that undergo a reversible ...
Artículo
ABP y tics adaptados a los laboratorios de prácticas de química física: su inserción e implementación
(Universidad de Sevilla, 2010)
El trabajo que se presenta está basado en la experiencia docente llevada a cabo en los grupos de laboratorio de las asignaturas Termodinámica Química y Experimentación en Química Física, de primer y segundo curso de la ...