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Artículo
Electrolytic synthesis of chloroacetic acids in a filter-press reactor from polychloromethanes
(Elsevier, 2010)
Electrochemical carboxylation of carbon tetrachloride and chloroform to synthesize chloroacetic acids in mild conditions has been investigated by galvanostatic electrolyses using a homemade electrochemical filter-press ...
Artículo
Solving the Hydration Structure of the Heaviest Actinide Aqua IonKnown: The Californium(III) Case
(Wiley-Blackwell, 2010)
Wish they all could be californium: X-ray absorption spectroscopy (black points) and Monte Carlo simulations (blue line) of Cf" in aqueous solutions have been combined to determine the ligand distance and coordination ...
Tesis Doctoral
Microsolvatación de cationes en disolución. Desarrollo del modelo de ion hidratado intercambiable y su aplicación a la química de cationes radiactivos
(2010-12-20)
Aqua ions, of general formula [M(H2O)n ] m+, are the most common structures adopted by metal cations, Mm+, when chemical conditions inhibit the formation of hydrolyzed and polymerized derivatives. 1 The implicit net charge, ...
Artículo
Microheterogeneous catalysis
(MDPI, 2010)
The catalytic effect of micelles, polymers (such as DNA, polypeptides) and nanoparticles, saturable receptors (cyclodextrins and calixarenes) and more complex systems (mixing some of the above mentioned catalysts) have ...
Artículo
Microscopic origins of the ferromagnetic exchange coupling in oxoverdazyl-based Cu(II) complex
(American Institute of Physics Publising LLC, 2010)
The exchange channels governing the experimentally reported coupling constant Jexpt=6 cm−1 value in the verdazyl-ligand based Cu II complex Cu hfac 2 imvdz are inspected using wave function-based difference dedicated ...
Tesis Doctoral
Propiedades espectroscópicas y fotofísicas de la Alfacarbolina. (9H-pirido[2,3-b]indol)
(2010)
El objetivo fundamental de esta Tesis es realizar un estudio detallado de las propiedades espectrales y fotofísicas de la AC a fin de comprobar si este substrato muestra también las mismas pautas de comportamiento que la ...
Artículo
A theoretical insight into the catalytic effect of a mixed-metal oxide at the nanometer level: The case of the highly active metal/CeOx/TiO2(110) catalysts
(AIP Publishing, 2010-03)
The structural and electronic properties of CeOx species supported on the rutile TiO2 110 surface have been examined by means of periodic density-functional calculations that use a generalized gradient approximation ...
Artículo
Molecular solids of actinide hexacyanoferrate: Structure and bonding
(IOP Publishing, 2010)
The hexacyanometallate family is well known in transition metal chemistry because the remarkable electronic delocalization along the metal-cyano-metal bond can be tuned in order to design systems that undergo a reversible ...
Tesis Doctoral
Simulación de la actividad del colorante en el proceso de captación de energía en celdas solares sensibilizadas
(2010-07-19)
En este trabajo se han estudiado mediante métodos cuánticos que se describen en el capítulo 1 diferentes aspectos relacionados con el funcionamiento y la eficiencia de las celdas solares sensibilizadas con colorantes ...