Author profile: Perejón Pazo, Antonio
Institutional data
Name | Perejón Pazo, Antonio |
Department | Química Inorgánica |
Knowledge area | Química Inorgánica |
Professional category | Profesor Titular de Universidad |
Request | |
Statistics
-
No. publications
96
-
No. visits
9582
-
No. downloads
16051
Publications |
---|
Article
Expanding the scope of multiphase-flash sintering: Multi-dogbone configurations and reactive processes
(Elsevier, 2024)
In this work, we have expanded the possibilities of the multiphase-flash sintering (MPFS) technique by investigating several ... |
Article
On the athermal origin of flash sintering: Separating field-induced effects from Joule heating using a current ramp approach
(Pergamon-Elsevier Science LTD, 2024)
Joule heating is generally acknowledged as the main driving force behind Flash Sintering. However, this view is challenged ... |
Article
Sodium acetate-based thermochemical energy storage with low charging temperature and enhanced power density
(Elsevier, 2024)
The electrification of heat necessitates the development of innovative domestic heat batteries to effectively balance ... |
Article
A generalized interface reaction kinetic model for describing heterogeneous processes driven by contracting mechanisms
(Springer, 2024)
The correct determination of the kinetic model and the kinetic parameters that describe a heterogeneous process is key ... |
Article
Flash Joule Heating-Boro/Carbothermal Reduction (FJH-BCTR): An approach for the instantaneous synthesis of transition metal diborides
(Elsevier, 2024)
Transition metal diborides (TMB2), such as ZrB2 and HfB2, are a class of ultra-high-temperature ceramics (UHTCs) that have ... |
Article
Structural, Mössbauer and Magnetic Study of (Mn0.2Co0.2Ni0.2Cu0.2X0.2)Fe2O4 (X=Fe, Mg) Spinel High-entropy Oxides Fabricated via Reactive Flash Sintering
(Elsevier, 2024)
Herein, it is reported the concomitant synthesis and sintering in a single step of (Mn0.2Co0.2Ni0.2Cu0.2X0.2)Fe2O4 (X=Fe, ... |
Article
Ca-based materials derived from calcined cigarette butts for CO2 capture and thermochemical energy storage
(Science Press, 2023)
Cigarette butts (CBs) are one of the most common types of litter in the world. Due to the toxic substances they contain, ... |
Article
Structural, Vibrational, and Magnetic Characterization of Orthoferrite LaFeO3 Ceramic Prepared by Reaction Flash Sintering
(Multidisciplinary Digital Publishing Institute (MDPI), 2023)
LaFeO3 perovskite ceramics have been prepared via reaction flash technique using Fe2O3 and La2O3 as precursors. The obtained ... |
Article
Determination of the Activation Energy Under Isothermal Conditions: Revisited
(Springer Nature, 2023)
The kinetic analysis of solid-state processes aims at obtaining fundamental information that can be used for predicting ... |
Article
Influence of Long-Term CaO Storage Conditions on the Calcium Looping Thermochemical Reactivity
(American Chemical Society, 2023)
Long-term storage capability is often claimed as one of the distinct advantages of the calcium looping process as a potential ... |
Article
Thermochemical Energy Storage Using Calcium Magnesium Acetates under Low CO2 Pressure Conditions
(Elsevier, 2023)
The calcium looping multicycle performance of CaO-based materials, derived from calcium magnesium acetates with different ... |
Article
Flexible Kinetic Model Determination of Reactions in Materials under Isothermal Conditions
(MDPI, 2023)
Kinetic analysis remains a powerful tool for studying a large variety of reactions, which lies at the core of material ... |
Article
Direct Comparison of Surface Crystal Growth Kinetics in Chalcogenide Glass Measured by Microscopy and DSC
(Wiley-Blackwell, 2023)
Surface crystallization in fine powder Se70Te30 chalcogenide glass was studied by differential scanning calorimetry (DSC) ... |
Article
Low Temperature Magnetic Transition of BiFeO₃ Ceramics Sintered by Electric Field-Assisted Methods: Flash and Spark Plasma Sintering
(MDPI, 2022)
Low temperature magnetic properties of BiFeO₃ powders sintered by flash and spark plasma sintering were studied. An anomaly ... |
Article
Albero: An alternative natural material for solar energy storage by the calcium-looping process
(Elsevier, 2022)
Large-scale thermochemical energy storage (TCES) is gaining relevance as an alternative to current thermal energy storage ... |
Article
A novel Multi‐Phase Flash Sintering (MPFS) technique for 3D complex‐shaped ceramics
(Elsevier, 2022)
This work demonstrates the first proof-of-concept of Multi-Phase Flash Sintering (MPFS). This novel tech- nique essentially ... |
Article
The SrCO3/SrO system for thermochemical energy storage at ultra-high temperature
(Elsevier, 2022)
Thermochemical energy storage (TCES) has attracted interest in the last years due to the possibility of attaining high ... |
Article
Flash Sintering Research Perspective: A Bibliometric Analysis
(MDPI, 2022)
Flash Sintering (FS), a relatively new Field-Assisted Sintering Technique (FAST) for ceramic processing, was proposed for ... |
Article
Effect of Steam Injection during Carbonation on the Multicyclic Performance of Limestone (CaCO3) under Different Calcium Looping Conditions: A Comparative Study
(American Chemical Society, 2022)
This study explores the effect of steam addition during carbonation on the multicyclic performance of limestone under ... |
Article
Influence of AC fields and electrical conduction mechanisms on the flash-onset temperature: Electronic (BiFeO3) vs. ionic conductors (8YSZ)
(Elsevier, 2022)
This work aims to clarify the influence of AC (up to 50 kHz) vs DC fields on the flash-onset temperature, emphasizing the ... |
Article
Steam-enhanced calcium-looping performance of limestone for thermochemical energy storage: The role of particle size
(Elsevier, 2022)
Steam injection has been proposed to attenuate the decay of CaO reactivity during calcium looping (CaL) under operating ... |
Article
Reactive flash sintering of SrFe12O19 ceramic permanent magnets
(Elsevier, 2022)
Reactive flash-sintering technique has been used in order to obtain strontium ferrite magnets from a mixture of SrCO3 and ... |
Article
Overlooked pitfalls in CaO carbonation kinetics studies nearby equilibrium: Instrumental effects on calculated kinetic rate constants
(Elsevier, 2022)
Due to its technological applications, such as CO2 capture, CaO carbonation kinetics has been extensively studied using a ... |
Article
Unveiling Mechanochemistry: kinematic-kinetic approach for the prediction of mechanically induced reactions
(Elsevier, 2021)
Mechanochemistry has attracted a lot of attention over the last few decades with a rapid growth in the number of publications ... |
Article
Kinetics and cyclability of limestone (CaCO3) in presence of steam during calcination in the CaL scheme for thermochemical energy storage
(Elsevier, 2021)
In the present work, we explore the use of steam in the CaCO3 calcination step of a calcium looping process devised for ... |
Article
Advanced parametrisation of phase change materials through kinetic approach
(Elsevier, 2021)
Phase change materials (PCM) have been widely investigated for heat storage and transfer applications. Numerous numerical ... |
Article
Calcination under low CO2 pressure enhances the Calcium Looping performance of limestone for thermochemical energy storage
(Elsevier, 2021)
The Calcium Looping performance of limestone for thermochemical energy storage has been investigated under novel favorable ... |
Final Degree Project
Compuestos basados en vanadio para el tratamiento de la diabetes
(2021)
El presente trabajo tiene como objetivo realizar una revisión bibliográfica de los diferentes compuestos de vanadio que ... |
Article
Paving the Way to Establish Protocols: Modeling and Predicting Mechanochemical Reactions
(American Chemical Society, 2021)
Parametrization of mechanochemical reactions, or relating the evolution of the reaction progress to the supplied input ... |
Article
Pure perovskite BiFeO3–BaTiO3 ceramics prepared by reaction flash sintering of Bi2O3–Fe2O3–BaTiO3 mixed powders
(Elsevier, 2021)
In this work, the 0.67BiFeO3-0.33BaTiO3 ferroelectric ceramic was prepared by Reaction Flash Sintering (RFS). This preparation ... |
Article
Relevance of particle size distribution to kinetic analysis: the case of thermal dehydroxylation of kaolinite
(Multidisciplinary Digital Publishing Institute (MDPI), 2021)
Kinetic models used for the kinetic analysis of solid-state reactions assume ideal conditions that are very rarely fulfilled ... |
Article
Calcium-Looping Performance of Biomineralized CaCO3 for CO2 Capture and Thermochemical Energy Storage
(ACS Publications, 2020)
The commercial deployment of calcium-looping (CaL)-based technologies relies on the availability of nontoxic, widely ... |
Article
Influence of DSC Thermal Lag on Evaluation of Crystallization Kinetics
(Elsevier, 2020)
Influence of added thermal resistance on crystallization kinetics, as measured by differential scanning calorimetry (DSC), ... |
Article
Development of a high-pressure thermobalance working under constant rate thermal analysis
(Springer Nature, 2020)
A thermogravimetric instrument that works at high pressure of different gases has been designed and assembled. The instrument ... |
Article
Influence of DSC thermal lag on evaluation of crystallization kinetics
(Elsevier, 2020)
Influence of added thermal resistance on crystallization kinetics, as measured by differential scanning calorimetry (DSC), ... |
Article
Role of particle size on the multicycle calcium looping activity of limestone for thermochemical energy storage
(Elsevier, 2020)
The calcium looping process, based on the reversible reaction between CaCO3 and CaO, is recently attracting a great deal ... |
Article
Anisotropic lattice expansion determined during flash sintering of BiFeO3 by in-situ energy-dispersive X-ray diffraction
(Elsevier, 2019)
BiFeO3 has a Curie temperature (TC) of 825 °C, making it difficult to sinter using conventional methods while maintaining ... |
Article
High-performance and low-cost macroporous calcium oxide based materials for thermochemical energy storage in concentrated solar power plants
(Elsevier, 2019)
High energy density, cycling stability, low cost and scalability are the main features required for thermochemical energy ... |
Article
Electrical properties of bismuth ferrites: Bi2Fe4O9 and Bi25FeO39
(Elsevier, 2019)
Bi2Fe4O9 was prepared by solid-state reaction and the electrical properties measured by impedance spectro- scopy. After ... |
Patent. Invention
Procedimiento termoquímico de almacenamiento de energía solar concentrada a partir de escoria de acería
(Oficina Española de Patentes y Marcas (OEPM), 2018)
La presente invención propone el empleo de escoria de acería pretratada para el almacenamiento termoquímico de energía ... |
Article
Calcium-Looping performance of mechanically modified Al2O3-CaO composites for energy storage and CO2 capture
(Elsevier B.V., 2018)
This work reports the Calcium-Looping (CaL) multicycle performance under energy storage and CO2 capture conditions of ... |
Article
Low-cost Ca-based composites synthesized by biotemplate method for thermochemical energy storage of concentrated solar power
(Elsevier BV, 2018)
An ever more environmentally conscious society demands the use of green, sustainable and high-efficiency renewable energy ... |
Article
Pressure Effect on the Multicycle Activity of Natural Carbonates and a Ca/Zr Composite for Energy Storage of Concentrated Solar Power
(American Chemical Society, 2018)
This work is focused on the use of the Calcium-Looping process (CaL) in Concentrated Solar Power (CSP) plants for ... |
Article
On the determination of thermal degradation effects and detection techniques for thermoplastic composites obtained by automatic lamination
(Elsevier, 2018)
Automatic lay-up and in-situ consolidation with thermoplastic composite materials is a technology under re- search for its ... |
Article
Phase-pure BiFeO3 produced by reaction flash-sintering of Bi2O3 and Fe2O3
(Royal Society of Chemistry, 2018)
Mixed powders of Bi2O3 and Fe2O3 are shown to yield single-phase, dense nanostructured polycrystals of BiFeO3 in reaction ... |
Article
Effect of milling mechanism on the CO2 capture performance of limestone in the Calcium Looping process
(Elsevier, 2018)
This work analyzes the relevant influence of milling on the CO2 capture performance of CaO derived from natural limestone. ... |
Article
Insight into the BiFeO3 flash sintering process by in-situ energy dispersive X-ray diffraction (ED-XRD)
(Elsevier, 2018)
The sintering mechanism of BiFeO3 has been investigated in-situ by energy dispersive X-ray diffraction (ED-XRD) using a ... |
Article
Crystallization Kinetics of Nanocrystalline Materials by Combined X-ray Diffraction and Differential Scanning Calorimetry Experiments
(American Chemical Society, 2018)
Crystallization is one key aspect in the resulting properties of nanocrystalline functional materials, and much effort has ... |
PhD Thesis
Mecanosíntesis y caracterización de materiales multiferroicos nanoestructurados.
(2017)
óxido mixto de hierro y bismuto, BiFeO3, con estructura tipo perovskita, es uno de los materiales magnetoeléctricos más ... |
Article
Large-scale high-temperature solar energy storage using natural minerals
(Elsevier, 2017)
The present work is focused on thermochemical energy storage (TCES) in Concentrated Solar Power (CSP) plants by means of ... |
Article
CO2 capture performance of Ca-Mg acetates at realistic Calcium Looping conditions
(Elsevier BV, 2017)
The Calcium Looping (CaL) process, based on the cyclic carbonation/calcination of CaO, has emerged in the last years as a ... |
Article
Characterization of mechanosynthesized Bi1−xSmxFeO3 samples unencumbered by secondary phases or compositional inhomogeneity
(Elsevier, 2017)
High-quality samples, in terms of phase purity and dielectric properties, of composition Bi1−xSmxFeO3 (0.05 ≤ x ≤ 0.20) ... |
Article
Multicycle activity of natural CaCO3 minerals for thermochemical energy storage in Concentrated Solar Power plants
(Elsevier Ltd, 2017)
Thermochemical energy storage in Concentrated Solar Power plants by means of the Calcium-Looping process is a promising ... |
Article
The Oxy-CaL process: A novel CO2 capture system by integrating partial oxy2 combustion with the Calcium-Looping process
(Elsevier, 2017)
This paper proposes a novel CO2 capture technology from the integration of partial oxy18 combustion and the Calcium Looping ... |
Article
Calcium-Looping performance of steel and blast furnace slags for thermochemical energy storage in concentrated solar power plants
(Elsevier BV, 2017)
The Calcium Looping (CaL) process, based on the carbonation/calcination of CaO, has been proposed as a feasible technology ... |
Article
Defect chemistry and electrical properties of BiFeO3
(Royal Society of Chemistry (Great Britain), 2017)
BiFeO attracts considerable attention for its rich functional properties, including room temperature coexistence of magnetic ... |
Article
Large-Scale Storage of Concentrated Solar Power from Industrial Waste
(American Chemical Society, 2017)
Deep penetration of renewable energies into the grid relies on the development of large-scale energy storage technologies ... |
Article
A Promising approach to the kinetics of crystallization processes: The sample controlled thermal analysis
(American Ceramic Society, 2017)
Constant Rate Thermal Analysis (CRTA) method implies controlling the temperature in such a way that the reaction rate is ... |
Article
Flash sintering of highly insulating nanostructured phase-pure BiFeO3
(American Ceramic Society, 2017)
We show that BiFeO, that is electrically homogeneous, is a good insulator, and has a low dielectric constant (the properties ... |
Article
Preparation of ytterbium substituted BiFeO3 multiferroics by mechanical activation
(Elsevier, 2017)
Samples in the system Bi1−xYbxFeO3 (0.02 ≤ × ≤ 0.07) have for the first time been prepared by mechanical activation followed ... |
Article
Effect of Thermal Pretreatment and Nanosilica Addition on Limestone Performance at Calcium-Looping Conditions for Thermochemical Energy Storage of Concentrated Solar Power
(American Chemical Society, 2017)
The share of renewable energies is growing rapidly, partly in response to the urgent need for mitigating CO emissions from ... |
Article
Effect of dolomite decomposition under CO2 on its multicycle CO2 capture behaviour under calcium looping conditions
(Royal Society of Chemistry, 2016)
One of the major drawbacks that hinder the industrial competitiveness of the calcium looping (CaL) process for CO capture ... |
Article
Magnesium hydride for energy storage applications: The kinetics of dehydrogenation under different working conditions
(Elsevier, 2016)
A new approach to the kinetics of magnesium hydride dehydrogenation is considered. A model able to predict the dehydrogenation ... |
Article
Influence of ball milling on CaO crystal growth during limestone and dolomite calcination: Effect on CO2 capture at Calcium Looping conditions
(American Chemical Society, 2016)
The multicycle CO2 capture performance of CaO derived from the calcination of ball-milled limestone and dolomite have been ... |
Article
Constant rate thermal analysis of a dehydrogenation reaction
(Royal Society of Chemistry, 2016)
The Constant Rate Thermal Analysis (CRTA) procedure has been employed for the first time to study the kinetics of MgH2 ... |
Article
Use of steel slag for CO2 capture under realistic calcium-looping conditions
(Royal Society of Chemistry, 2016)
In this study, CaO derived from steel slag pretreated with diluted acetic acid has been tested as a dry sorbent for CO ... |
Article
The Calcium-Looping technology for CO2 capture: On the important roles of energy integration and sorbent behavior
(Elsevier, 2016)
The Calcium Looping (CaL) technology, based on the multicyclic carbonation/calcination of CaO in gas–solid fluidized bed ... |
Article
On the relevant role of solids residence time on their CO2 capture performance in the Calcium Looping technology
(Pergamon Press, 2016)
The multicycle CO capture performance of CaO derived from natural limestone and dolomite has been investigated by means ... |
Article
Combined TGA-MS kinetic analysis of multistep processes. Thermal decomposition and ceramification of polysilazane and polysiloxane preceramic polymers.
(2016)
The polymer-to-ceramic transformation kinetics of two widely employed ceramic precursors; 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane ... |
Article
New insights on the kinetic analysis of isothermal data: The independence of the activation energy from the assumed kinetic model
(American Chemical Society, 2015)
Isothermal experiments are widely employed to study the kinetics of solid-state reactions or processes to extract essential ... |
Article
Preparation of phase pure, dense fine grained ceramics by conventional and spark plasma sintering of La-substituted BiFeO3 nanoparticles
(Elsevier, 2015)
High density ceramics of the system Bi1−xLaxFeO3, 0 ≤ x ≤ 0.15, have been prepared starting from nanoparticles obtained ... |
Article
Thermal decomposition of dolomite under CO2: insights from TGA and in situ XRD analysis
(Royal Society of Chemistry, 2015)
Thermal decomposition of dolomite in the presence of CO2 in a calcination environment is investigated by means of in situ ... |
Article
Scission kinetic model for the prediction of polymer pyrolysis curves from chain structure
(Elsevier, 2014)
There is a significant interest in correlating polymer structure with thermal degradation behavior. Thus, polymer pyrolysis ... |
Article
Constant rate thermal analysis for enhancing the long-term CO2 capture of CaO at Ca-looping conditions
(Elsevier, 2013)
Experimental results are reported on the (Ca-looping) multicyclic CO2 capture of CaO and nanosilica/CaO composites derived ... |
Article
Pyrolysis kinetics of ethylene-propylene (EPM) and ethylene-propylene-diene (EPDM)
(Elsevier, 2013)
The thermal degradation kinetics of several ethylene-propylene copolymers (EPM) and ethylene-propylene-diene terpolymers ... |
Article |
Article
Generalized master plots as a straightforward approach for determining the kinetic model: The case of cellulose pyrolysis
(Elsevier, 2013)
The thermal degradation of cellulose is a complex reaction and, despite the large amount of work by many investigators ... |
Article
Clarifications regarding the use of model-fitting methods of kinetic analysis for determining the activation energy from a single non-isothermal curve
(Chemistry Central, 2013)
Abstract Background This paper provides some clarifications regarding the use of model-fitting methods of kinetic analysis ... |
Article
Limitations of model-fitting methods for kinetic analysis: Polystyrene thermal degradation
(Elsevier, 2013)
In this paper, some clarifications regarding the use of model-fitting methods of kinetic analysis are provided in response ... |
Article
Kinetic studies in solid state reactions by sample-controlled methods and advanced analysis procedures
(Akadémiai Kiadó (Budapest), 2013)
A comparative study of both conventional rising temperature and sample-controlled methods, like constant rate thermal ... |
Article
Direct mechanosynthesis of pure BiFeO3 perovskite nanoparticles: reaction mechanism
(Royal Society of Chemistry (Great Britain), 2013)
In this work, a mechanochemical procedure is proposed as a simple and fast method to synthesize the pure BiFeO3 perovskite ... |
Article
CO2 multicyclic capture of pretreated/doped CaO in the Ca-looping process. Theory and experiments
(Royal Society of Chemistry (Great Britain), 2013)
We study in this paper the conversion of CaO-based CO2 sorbents when subjected to repeated carbonation/calcination cycles ... |
Article
Electrical properties of stoichiometric BiFeO3 prepared by mechanosynthesis with either conventional or spark plasma sintering
(Wiley, 2013)
Phase-pure powders of stoichiometric BiFeO3 have been prepared by mechanosynthesis. Ceramics sintered by either conventional ... |
Article
Role of looping-calcination conditions on self-reactivation of thermally pretreated CO2 sorbents based on CaO
(American Chemical Society, 2013)
The conversion of thermally pretreated CaO along successive carbonation/calcination cycles has been investigated, as ... |
PhD Thesis
Mecanosíntesis y caracterización de los materiales multiferroicos nanoestructurados Bi(1-x)RxFeO3 (R=La, Y)
(2012)
En la presente tesis doctoral se aborda la preparación, por métodos mecanoquímicos, de materiales multiferroicos, entendiéndose ... |
Article
Nanoclay nucleation effect in the thermal stabilization of a polymer nanocomposite: A kinetic mechanism change
(American Chemical Society, 2012)
The enhanced thermal stability of polymer-clay nanocomposites over the original polymers is one of their most interesting ... |
Presentation
Enhancement of fast CO2Capture by a Nano-SiO2/CaO composite atCa-Looping conditions
(CHISA, 2012)
In this paper we show the performance of a new CO2sorbentconsisting of a dry physical mixture of a Ca-based sorbent and a ... |
Article
Kinetic analysis of complex solid-state reactions. A new deconvolution procedure
(American Chemical Society, 2011)
The kinetic analysis of complex solid-state reactions that involve simultaneous overlapping processes is challenging. A ... |
Article
Constant rate thermal analysis for thermal stability studies of polymers
(Elsevier, 2011)
This paper explores the relationship between the shapes of temperature-time curves obtained from experimental data recorded ... |
Article
Study of the dehydroxylation-rehydroxylation of pyrophyllite
(American Ceramic Society, 2010)
Pyrophyllite is a raw material of significant interest due to its large number of applications. Most of these applications ... |
Article
Quantitative characterization of multicomponent polymers by sample-controlled thermal analysis
(American Chemical Society, 2010)
This paper explores the potential of sample-controlled thermal analysis (SCTA) in order to perform compositional analysis ... |
Article
A new model for the kinetic analysis of thermal degradation of polymers driven by random scission
(Elsevier, 2010)
In this paper, a series of f(α) kinetic equations able to describe the random scission degradation of polymers is formulated ... |
Article
Mechanochemical preparation of BaTiO3-Ni nanocomposites with high dielectric constant
(Elsevier, 2010)
A mechanochemical procedure is proposed for an easy preparation of a BaTiO3-Ni composite in a single step. BaTiO3 and Ni ... |
Article
Generalized kinetic master plots for the thermal degradation of polymers following a random scission mechanism
(American Chemical Society, 2010)
In this paper, the f(α) conversion functions for random scission mechanisms have been proposed to allow for the construction ... |
Article
Kinetic model for thermal dehydrochlorination of poly(vinyl chloride)
(Elsevier, 2010)
In this paper, a novel method for calculating degradation kinetics is presented. The method has been applied to the thermal ... |
Article
Combined kinetic analysis of thermal degradation of polymeric materials under any thermal pathway
(Elsevier, 2009)
Combined kinetic analysis has been applied for the first time to the thermal degradation of polymeric materials. The ... |