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Tesis Doctoral
Síntesis y propiedades de diversos complejos de molibdeno con ligandos nitrosilo y dihidrobis(pirazolil)borato y de algunos elementos muy electropositivos con ciclopentadienilos voluminosos
(2000)
La presente Tesis Doctoral corresponde a dos áreas de la Química Organometálica entre las que existen diferencias suficientemente importantes como para que se aconsejable su distribución en dos capítulos distintos. En uno ...
Artículo
Preparación, estudio potenciométrico y de estabilidad térmica de los complejos de Ti(IV), V(V), V(IV), Cr(III), Fe(III) y Co(III) con el ADCT
(Real Sociedad Española de Física y Química, 1976)
Artículo
Electronic and structural effects of low-hapticity coordination of arene rings to transition metals
(American Chemical Society, 2014)
A DFT computational study and a structural analysis of the coordination of arenes to transition metals in low -hapticity (η1 and η2) modes have been developed, including a pseudosymmetry analysis of the molecular orbitals ...
Artículo
Electron-rich metal complexes for C02 and CS2 incorporation
(Walter de Gruyter GmbH, 1989)
The dihapto coordination of two molecules of carbon dioxide to a square-planar MoP2(P-P) fragment (P=monodentate-, P-P=bidentate phosphi- ne ligands) can occur in several ways giving rise to different conformers. Compounds ...
Artículo
An Unsaturated Four-Coordinate Dimethyl Dimolybdenum Complex with a Molybdenum–Molybdenum Quadruple Bond
(John Wiley & Sons, 2017)
We describe the synthesis and the molecular and electronic structures of the complex [Mo2Me2{μ‐HC(NDipp)2}2] (2; Dipp=2,6‐iPr2C6H3), which contains a dimetallic core with an Mo–Mo quadruple bond and features uncommon ...
Artículo
Base-Promoted, Remote C−H Activation at a Cationic (η5 ‑C5Me5)Ir(III) Center Involving Reversible C−C Bond Formation of Bound C5Me5
(American Chemical Society, 2019)
C-H bond activation at cationic [(η5-C5Me5)Ir(PMe2Ar')] centers is described, where PMe2Ar' are the terphenyl phosphine ligands PMe2ArXyl2 and PMe2ArDipp2. Different pathways are defined for the conversion of the five-coordinate ...
Artículo
Reactivity of a trans-[H-Mo≣Mo-H] Unit Towards Alkenes and Alkynes. Bimetallic Migratory Insertion, H-Elimination and Other Reactions
(Royal Society of Chemistry, 2018)
Complex [Mo2(H)2{μ-HC(NDipp)2}2(THF)2], (1·THF), reacts with C2H4 and PhCH[double bond, length as m-dash]CH2 to afford hydrido-hydrocarbyl and bis(hydrocarbyl) derivatives of the Mo[quadruple bond, length as m-dash]Mo bond. ...
Tesis Doctoral
Reactivity of Quadruply Bonded Dimolybdenum Hydride Centres: Elementary Organometallic Reactions and Coordination to Main-Group Metal‒Carbon and Metal‒Hydrogen Bonds
(2021-07-08)
En esta Tesis se investigan complejos bimetálicos de molibdeno estabilizados por ligandos amidinato bidentados voluminosos (AdDipp2). La síntesis del complejo [Mo2(H)2(μ-AdDipp2)2(thf)2] (1·thf) se ha mejorado y además ...
Artículo
Methyl Complexes of the Transition Metals
(John Wiley & Sons, 2016)
Organometallic chemistry can be considered as a wide area of knowledge that combines concepts of classic organic chemistry, that is, based essentially on carbon, with molecular inorganic chemistry, especially with coordination ...