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Artículo
Influence of gold particle size in Au/C catalysts for base-free oxidation of glucose
(Elsevier, 2017)
A series of gold colloids were prepared and immobilized on commercial activated carbon. The influence of the colloid preparation and stability were studied and related to the gold particle size in the final catalyst. The ...
Artículo
WGS and CO-PrOx reactions using gold promoted copper-ceria catalysts: “bulk CuO-CeO2 vs. CuO-CeO2/Al2O3 with low mixed oxide content”
(Elsevier, 2016)
A copper-ceria bulk catalyst has been compared to a series of catalysts designed according to the as called “supported approach”, corresponding to the dispersion of low content mixed copper-ceria oxide on alumina matrix. ...
Artículo
Iron-modified ceria and Au/ceria catalysts for Total and Preferential Oxidation of CO (TOX and PROX)
(Elsevier, 2010)
Iron-modified ceria supports containing different molar percentages of Fe (0%, 10%, 25%, and 50%) were synthesized by thermal decomposition of the metal propionates. The formation of a Ce-Fe oxide solid solution is evidenced ...
Artículo
Could an efficient WGS catalyst be useful in the CO-PrOx reaction?
(Elsevier, 2014)
This work presents an evaluation of a high performance series of water gas shift (WGS) catalysts in the preferential CO oxidation reaction (PrOx) in order to examine the applicability of the same catalyst for both processes ...
Artículo
Au-supported on Fe-doped ceria solids prepared in water-in-oil microemulsions: Catalysts for CO oxidation
(Elsevier, 2016)
Gold catalysts were synthesized by deposition-precipitation employing Fe-doped ceria systems, previously obtained by means of the water-in-oil microemulsions methodology with different iron contents (10, 25 and 50 Fe at.%). ...
Artículo
Gold supported on metal-doped ceria catalysts (M = Zr, Zn and Fe) for the preferential oxidation of CO (PROX)
(Academic Press, 2010)
A series of ceria oxides doped with 10 mol.% of Zr, Zn and Fe have been prepared by a pseudo sol-gel method throughout the thermal decomposition of the corresponding metallic propionates. With these supports, 1 wt.% gold ...
Artículo
The role of Au, Cu & CeO2 and their interactions for an enhanced WGS performance
(Elsevier, 2016)
The WGS reaction over multicomponent Au/Ce1-xCuxO2/Al2O3 catalysts is studied in this work. The systems are carefully designed aiming to take advantage of every active phase included in the formulation: gold, ceria and ...
Artículo
Boosting the activity of a Au/CeO2/Al2O3 catalyst for the WGS reaction
(Elsevier, 2015)
Herein a strategy to design highly efficient Au/CeO2/Al2O3 based WGS catalysts is proposed. The inclusion of transition metals, namely Fe, Cu and Zn as CeO2 dopant is considered. All the promoters successfully increased ...
Artículo
H2 oxidation as criterion for PrOx catalyst selection: Examples based on Au-CoOx-supported systems
(Elsevier, 2015-06-01)
A new approach for understanding PrOx reaction over gold catalysts is proposed in this work. The competition between H2 and CO oxidation has been studied over a series of Au/MOx/Al2O3 (M = Ce and Co) catalysts in simulated ...
Artículo
Au/CeO2 metallic monolith catalysts: Influence of the metallic substrate
(World Gold Council, 2013)
Ceria-based gold catalysts were successfully deposited on ferritic stainless steel (Fecralloy) and aluminium monoliths. The prepared monolithic and reference powder catalysts were characterized by means of S BET, X-ray ...