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Artículo
Does shaping catalysts modify active phase sites? A comprehensive in situ FTIR spectroscopic study on the performance of a model Ru/Al2O3 catalyst for the CO methanation
(Elsevier, 2018)
Routinely, it seems assumed that the catalytic layer coated on monoliths and microchannel reactors preserve the properties of the initial powder catalyst. However, this assumption should be reasonably demonstrated since ...
Artículo
Promoting effect of CeO2, ZrO2 and Ce/Zr mixed oxides on Co/Γ-Al2O3 catalyst for Fischer-Tropsch synthesis
(Elsevier, 2019)
A series of cobalt-based catalysts have been synthesized using as support γ-Al2O3 promoted by ceria/zirconia mixed oxides with a variable Ce/Zr molar ratio. The obtained catalysts demonstrated oxide promotion results in ...
Artículo
Selective CO removal over Au/CeFe and CeCu catalysts in microreactors studied through kinetic analysis and CFD simulations
(Elsevier, 2011)
A kinetic study of the preferential oxidation of CO in H2 rich streams (CO-PrOx) over a cerium-copper oxide (CeCu) and a gold catalyst supported on cerium-iron oxide (Au/CeFe) is presented. The gold catalyst is very active ...
Artículo
Au/CeO2 catalysts: structure and CO oxidation activity
(Multidisciplinary Digital Publishing Institute (MDPI), 2016)
In this comprehensive review, the main aspects of using Au/CeO2 catalysts in oxidation reactions are considered. The influence of the preparation methods and synthetic parameters, as well as the characteristics of the ceria ...
Artículo
Phosphate-type supports for the design of WGS catalysts
(Elsevier, 2018)
The importance of water availability during the WGS reaction has been extensively reported. Thus, the search of new supports able to interact with the water molecule is of great importance. In this work, a series of ...
Artículo
Design and testing of a microchannel reactor for the PROX reaction
(Elsevier, 2011)
The different steps for manufacturing a microchannel reactor for the PROX reaction are discussed. Transient Liquid Phase bonding (TLP) using a Ni-B-Si amorphous melt spun is used for joining micromilled Al-alloyed ferritic ...
Artículo
Oxidation of CO over gold supported on Zn-modified ceria catalysts
(Elsevier, 2011)
A series of Zn-modified ceria solids were prepared by thermal decomposition of the corresponding metal propionates. The formation of segregated ZnO particles on the ceria surface is evidenced for these solids using X-ray ...
Artículo
Surface oxygen vacancies in gold based catalysts for CO oxidation
(RSC Publishing, 2014)
Experimental catalytic activity measurements, Diffuse Reflectance Infrared Fourier Spectroscopy, and Density Functional Theory calculations are used to investigate the role and dynamics of surface oxygen vacancies in the ...
Artículo
Fe-doped ceria solids synthesized by the microemulsion method for CO oxidation reactions
(Elsevier, 2011)
A series of Ce-Fe mixed oxides as well as the pure oxides were synthesized by the microemulsions method. The solid solution formation was established for all the Fe-doped systems and only a hardly noticeable segregation ...
Artículo
Policies and Motivations for the CO2 Valorization through the Sabatier Reaction Using Structured Catalysts. A Review of the Most Recent Advances
(MDPI, 2018-11)
The current scenario where the effects of global warming are more and more evident, has motivated different initiatives for facing this, such as the creation of global policies with a clear environmental guideline. Within ...