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Artículo
N-substituted Aminobiphenyl Palladacycles Stabilized by Dialkylterphenyl Phosphanes: Preparation and Applications in C[sbnd]N Cross-coupling Reactions
(Elsevier, 2021)
Neutral and cationic N-methyl- and N-phenyl-2-aminobiphenyl methanesulfonate palladacycles stabilized with dialkylterphenyl phosphanes have been prepared and characterized. Neutral structures are favored with the less bulky ...
Artículo
A Cationic Unsaturated Platinum(II) Complex that Promotes the Tautomerization of Acetylene to Vinylidene
(Wiley-VCH, 2017)
Complex [PtMe(PMeAr)] (1), which contains a tethered terphenyl phosphine (Ar =2,6-(2,6-PrCH)CH), reacts with [H(EtO)]BAr (BAr =B[3,5-(CF)CH] ) to give the solvent (S) complex [PtMe(S)(PMeAr)] (2⋅S). Although the solvent ...