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Mostrando ítems 1-4 de 4
Artículo
Supported σ-Complexes of Li−C Bonds from Coordination of Monomeric Molecules of LiCH3, LiCH2CH3 and LiC6H5 to Mo≣Mo Bonds
(German Chemical Society, 2022)
LiCH3 and LiCH2CH3 react with the complex [Mo2(H)2(μ-AdDipp2)2(thf)2] (1⋅thf) with coordination of two molecules of LiCH2R (R=H, CH3) and formation of complexes [Mo2{μ-HLi(thf)CH2R}2(AdDipp2)2], 5⋅LiCH3 and 5⋅LiCH2CH3, ...
Artículo
Unmasking the constitution and bonding of the proposed lithium nickelate “Li3NiPh3(solv)3”: revealing the hidden C6H4 ligand
(Royal Society of Chemistry, 2022)
More than four decades ago, a complex identified as the planar homoleptic lithium nickelate “Li3NiPh3(solv)3” was reported by Taube and co-workers. This and subsequent reports involving this complex have lain dormant since; ...
Artículo
N-substituted Aminobiphenyl Palladacycles Stabilized by Dialkylterphenyl Phosphanes: Preparation and Applications in C[sbnd]N Cross-coupling Reactions
(Elsevier, 2021)
Neutral and cationic N-methyl- and N-phenyl-2-aminobiphenyl methanesulfonate palladacycles stabilized with dialkylterphenyl phosphanes have been prepared and characterized. Neutral structures are favored with the less bulky ...
Tesis Doctoral
Reactivity of Quadruply Bonded Dimolybdenum Hydride Centres: Elementary Organometallic Reactions and Coordination to Main-Group Metal‒Carbon and Metal‒Hydrogen Bonds
(2021-07-08)
En esta Tesis se investigan complejos bimetálicos de molibdeno estabilizados por ligandos amidinato bidentados voluminosos (AdDipp2). La síntesis del complejo [Mo2(H)2(μ-AdDipp2)2(thf)2] (1·thf) se ha mejorado y además ...