Buscar
Mostrando ítems 1-8 de 8
Artículo
Synthesis and characterization of chiral bidentate bis(N-heterocyclic carbene)-carboxylate palladium and nickel complexes
(Elsevier, 2022)
Complexes [Pd{(S)-NHCMes,R}2] (R = Me, 2a; iPr, 2b; iBu, 2c) and [Pd{(R)-NHCMes,Me}2] (2a’) were prepared by reaction of the corresponding imidazolium precursor [ImMes,R] (namely (S)–2-alkyl(3-mesityl-1H-imidazol-3- iu ...
Artículo
Development of a high-pressure thermobalance working under constant rate thermal analysis
(Springer Nature, 2020)
A thermogravimetric instrument that works at high pressure of different gases has been designed and assembled. The instrument has been devised to work in a temperature range from room temperature to 1000 °C in various ...
Artículo
Elucidating the Promotional Effect of Cerium in the Dry Reforming of Methane
(Wiley-Blackwell, 2021)
A series of Ni-Ce catalysts supported on SBA-15 has been prepared by co-impregnation, extensively characterized and evaluated in the carbon dioxide reforming of methane (DRM). The characterization by TEM, XRD and TPR has ...
Artículo
Nickel and Palladium Complexes with Reactive σ-Metal-Oxygen Covalent Bonds
(Wiley-Blackwell, 2020)
This article reviews the chemistry of nickel and palladium complexes with terminally bound hydroxide and alkoxide ligands. The research carried out in our group is discussed in the context of the general literature. It is ...
Artículo
Nucleophilic Nickel and Palladium Pincer Hydroxides: A Study of Their Reactions with Dimethyl Carbonate and Other Non-Alkylating Organic Electrophiles
(Wiley-Blackwell, 2021)
The reactions of the pincer hydroxide complexes [(iPrPCP)M(OH)] (M=Ni, Pd) with dimethyl carbonate (DMC), and a set of organic electrophiles including benzaldehyde have been investigated in the context of our ongoing ...
Artículo
Synthesis, characterisation and crystal structure of a three-dimensional network of an h-bonded Ni (II) Hexametylenetetramine complex
(Royal Society of Chemistry, 2010)
A three-dimensional network of H-bonding nickel (II) hexamethylenetetramine complex has been synthesized and characterised and its structure determined by single crystal X-ray diffraction studies which show that ...
Artículo
Lafeo3 modified with ni for hydrogen evolution via photocatalytic glucose reforming in liquid phase
(Multidisciplinary Digital Publishing Institute (MDPI), 2021)
In this work, the optimization of Ni amount on LaFeO3 photocatalyst was studied in the photocatalytic molecular hydrogen production from glucose aqueous solution under UV light irradiation. LaFeO3 was synthesized via ...
Artículo
Cleavage of Carbon Dioxide C=O Bond Promoted by Nickel-Boron Cooperativity in a PBP-Ni Complex
(Wiley-Blackwell, 2023)
The synthesis and characterization of (tBuPBP)Ni(OAc) (5) by insertion of carbon dioxide into the Ni−C bond of (tBuPBP)NiMe (1) is presented. An unexpected CO2 cleavage process involving the formation of new B−O and Ni−CO ...