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Artículo
New 3D Printing Strategy for Structured Carbon Devices Fabrication
(MDPI, 2023)
This work shows a new method for the preparation of 100% carbon-structured devices. The method is based on resorcinol-formaldehyde polymerization, using starch as a binder with the addition of a certain amount of external ...
Artículo
Unravelling the Role of Oxygen Vacancies in the Mechanism of the Reverse Water–Gas Shift Reaction by Operando DRIFTS and Ultraviolet–Visible Spectroscopy
(American Chemical Society, 2018)
The reaction mechanism of the reverse water−gas shift (RWGS) reaction was investigated using two commercial gold-based catalysts supported on Al2O3 and TiO2. The surface species formed during the reaction and reaction ...
Artículo
Aluminium(iii) dialkyl 2,6-bisimino-4R-dihydropyridinates(−1): selective synthesis, structure and controlled dimerization
(Royal Society of Chemistry, 2019)
A family of stable and otherwise selectively unachievable 2,6-bisimino-4-R-1,4-dihydropyridinate aluminium (III) dialkyl complexes [AlR’2(4-R-i PrBIPH)] (R = Bn, Allyl; R’ = Me, Et, i Bu) have been synthesized, taking ...
Artículo
Multicomponent Ni-CeO2 nanocatalysts for syngas production from CO2/CH4 mixtures
(Elsevier, 2018)
The dry reforming of methane with CO2 is a common route to transform CO2/CH4 mixtures into added value syngas. Ni based catalysts are highly active for this goal but suffer from deactivation, as such promoters need to be ...
Artículo
Rhodium(I) Complexes with Ligands Based on N-Heterocyclic Carbene and Hemilabile Pyridine Donors as Highly E Stereoselective Alkyne Hydrosilylation Catalysts
(American Chemical Society, 2017)
Cationic rhodium(I) complexes containing picolyl-NHC (NHC = N-heterocyclic carbene) ligands that differ in the substitution at the 6-position of the pyridine donor serve as efficient E-selective alkyne hydrosilylation ...
Artículo
Double asymmetric hydrogenation of conjugated dienes: a self-breeding chirality route for C2 symmetric 1,4-diols
(Royal Society of Chemistry, 2019)
The synthesis and double asymmetric hydrogenation of (Z,Z)-1,3- diene-1,4-diyl diacetates is described. In this reaction C2/meso ratios up to 85 : 15 and enantioselectivities up to 97% ee have been achieved. As the ...
Artículo
Influence of ball milling on CaO crystal growth during limestone and dolomite calcination: Effect on CO2 capture at Calcium Looping conditions
(American Chemical Society, 2016)
The multicycle CO2 capture performance of CaO derived from the calcination of ball-milled limestone and dolomite have been tested under high temperature and high CO2 concentration environment for the first time. Here it ...
Artículo
Pressure Effect on the Multicycle Activity of Natural Carbonates and a Ca/Zr Composite for Energy Storage of Concentrated Solar Power
(American Chemical Society, 2018)
This work is focused on the use of the Calcium-Looping process (CaL) in Concentrated Solar Power (CSP) plants for Thermochemical Energy Storage (TCES). Cheap, abundant and nontoxic natural carbonate minerals, such as ...
Artículo
Tailoring the Band Gap in the ZnS/ZnSe System: Solid Solutions by a Mechanically Induced Self-Sustaining Reaction
(American Chemical Society, 2019)
The complete ZnSxSe1−x solid solution was successfully obtained by the mechanochemical process denoted as a mechanically induced self-sustaining reaction. Excellent control of the chemical stoichiometry of the solid ...
Artículo
Electrophilic activation of alkynes promoted by a cationic alkylidene complex of Pt(II)
(Royal Society of Chemistry, 2022-03-18)
Pt(II) alkylidene 1a has been reacted with terminal alkynes to afford ylide complexes 3a-d, resulting from electrophilic activation of the C≡C bond and its insertion into the platinacyclic fragment of 1a that contains the ...