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Artículo
Active role of the buffer in the proton-coupled electron transfer of immobilized iron porphyrins
(American Chemical Society, 2021-01)
Evaluation of the proton-coupled electron transfer thermodynamics of immobilized hemin is challenging due to the disparity of its electrochemical titration curves reported in the literature. Deviations from the one-electron, ...
Artículo
Cobalt metal-organic framework based on layered double nanosheets for enhanced electrocatalytic water oxidation in neutral media
(American Chemical Society, 2020)
A new cobalt metal-organic framework (2D-Co-MOF) based on well-defined layered double cores that are strongly connected by intermolecular bonds has been developed. Its 3D structure is held together by π-π stacking interactions ...
Artículo
Bimetallic Intersection in PdFe@FeOx-C Nanomaterial for Enhanced Water Splitting Electrocatalysis
(Wiley-Blackwell, 2022)
Supported Fe-doped Pd-nanoparticles (NPs) are prepared via soft transformation of a PdFe-metal oraganic framework (MOF). The thus synthesized bimetallic PdFe-NPs are supported on FeOx@C layers, which are essential for ...
Artículo
Structural and functional insights into lysine acetylation of cytochrome c using mimetic point mutants
(Wiley-Blackwell, 2021)
Post-translational modifications frequently modulate protein functions. Lysine acetylation in particular plays a key role in interactions between respiratory cytochrome c and its metabolic partners. To date, in vivo ...
Artículo
Enzyme-like activity of cobalt-MOF nanosheets for hydrogen peroxide electrochemical sensing
(Elsevier, 2022-10)
Metal-organic frameworks (MOFs) are receiving increased attention as new functional nanomaterials for the development of electrochemical sensors. Herein, we develop an electrochemical platform for non-enzymatic hydrogen ...