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Mostrando ítems 21-30 de 54
Artículo
A new model for the kinetic analysis of thermal degradation of polymers driven by random scission
(Elsevier, 2010)
In this paper, a series of f(α) kinetic equations able to describe the random scission degradation of polymers is formulated in such a way that the reaction rate of the thermal degradation of polymers that go through a ...
Artículo
Relevant influence of limestone crystallinity on CO2 capture in the Ca-looping technology at realistic calcination conditions
(American Chemical Society, 2014)
We analyze the role of limestone crystallinity on its CO2 capture performance when subjected to carbonation/calcination cycles at conditions mimicking the Ca-looping (CaL) technology for postcombustion CO 2 capture. The ...
Artículo
Limestone calcination nearby equilibrium: Kinetics, CaO crystal structure, sintering and reactivity
(American Chemical Society, 2015)
In this work, we analyze limestone calcination kinetics at environmental conditions involving a CO2 partial pressure P close to the equilibrium pressure Peq by means of in situ X-ray diffraction (XRD) and thermogravimetric ...
Artículo
Influence of AC fields and electrical conduction mechanisms on the flash-onset temperature: Electronic (BiFeO3) vs. ionic conductors (8YSZ)
(Elsevier, 2022)
This work aims to clarify the influence of AC (up to 50 kHz) vs DC fields on the flash-onset temperature, emphasizing the role of the electrical conduction mechanism. BiFeO3 (BFO) is used as an example of electronic conductor ...
Artículo
Characterization of thermally stable gamma alumina fibres biomimicking sisal
(Elsevier, 2014)
Mesoporous gamma alumina fibres of high surface area, stable up to 1000°C, were synthesized by bioreplica technique using sisal fibres as templates. Alumina formation during pyrolysis and calcination of fibres infiltrated ...
Artículo
Effect of heat pretreatment/recarbonation in the Ca-looping process at realistic calcination conditions
(American Chemical Society, 2014)
Even though an increasing number of pilot-scale plants are demonstrating the potential efficiency of the Ca-looping technology to capture CO2 at a commercial level, a still standing matter of concern is the loss of carbonation ...
Artículo
Determination of the Activation Energy Under Isothermal Conditions: Revisited
(Springer Nature, 2023)
The kinetic analysis of solid-state processes aims at obtaining fundamental information that can be used for predicting the time evolution of a process within a wide range of conditions. It is an extended belief that the ...
Artículo
Steam-enhanced calcium-looping performance of limestone for thermochemical energy storage: The role of particle size
(Elsevier, 2022)
Steam injection has been proposed to attenuate the decay of CaO reactivity during calcium looping (CaL) under operating conditions compatible with carbon capture and storage. However, it is yet unknown whether the perceived ...
Artículo
Advanced parametrisation of phase change materials through kinetic approach
(Elsevier, 2021)
Phase change materials (PCM) have been widely investigated for heat storage and transfer applications. Numerous numerical simulation approaches have been proposed for modelling their behaviour and predicting their performance ...
Artículo
Calcination under low CO2 pressure enhances the Calcium Looping performance of limestone for thermochemical energy storage
(Elsevier, 2021)
The Calcium Looping performance of limestone for thermochemical energy storage has been investigated under novel favorable conditions, which involve calcination at moderate temperatures under CO2 at low pressure (0.01 and ...