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Mostrando ítems 1-8 de 8
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Artículo
Activation of Si-H and B-H bonds by Lewis acidic transition metals and p-block elements: same, but different
Ríos Moreno, Pablo; Rodríguez, Amor; Conejero, Salvador (Royal Society of Chemistry, 2022)In this Perspective we discuss the ability of transition metal complexes to activate and cleave the Si–H and B–H bonds of ...
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Bonding Situation of σ-E−H Complexes in Transition Metal and Main Group Compounds
Ríos Moreno, Pablo; Conejero, Salvador; Fernández, Israel (Wiley-Blackwell, 2022)The ambiguous bonding situation of σ-E−H (E=Si, B) complexes in transition metal compounds has been rationalized by means ...
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Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation
Ríos Moreno, Pablo; Díez, Josefina; López Serrano, Joaquín; Rodríguez, Amor; Conejero, Salvador (John Wiley & Sons, 2016)The low-electron-count cationic platinum complex [Pt(ItBu’)(ItBu)][BAr], 1, interacts with primary and secondary silanes ...
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Enhancing the catalytic properties of well-defined electrophilic platinum complexes
Ríos Moreno, Pablo; Rodríguez, Amor; Conejero, Salvador (Royal Society of Chemistry, 2020)Platinum complexes have been often considered as the least reactive of the group 10 triad metals. Slow kinetics are behind ...
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Formation of C−X Bonds Through Stable Low-Electron Count Cationic Pt(IV) Alkyl Complexes Stabilized by N-Heterocyclic Carbenes
Rivada Wheelaghan, Orestes; Roselló Merino, Marta; Díez, Josefina; Maya Díaz, Celia María; López Serrano, Joaquín; Conejero, Salvador (American Chemical Society, 2014)Cationic five-coordinate Pt(IV) alkyl complexes stabilized by bulky N-heterocyclic carbenes have been isolated and fully ...
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Ligand Effects in Carbon−Boron Coupling Processes Mediated by σ-BH Platinum Complexes
Ríos Moreno, Pablo; Fernández de Córdova, Francisco José; Borge, Javier; Curado, Natalia; Lledós, Agustí; Conejero, Salvador (Wiley, 2021)The reaction of tri-coordinated boranes (derived from dioxaborolanes and diazaborolanes) with cyclometalated low-electron ...
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Platinum nanoparticles stabilized by N-heterocyclic thiones. Synthesis and catalytic activity in mono- and di-hydroboration of alkynes
Moraes Teixeira, Leonardo César de; Figueiredo, Rute C.; Espinós Manzorro, Juan Pedro; Vattier Lagarrigue, María Florencia; Franconetti García, Antonio; Jaime, Carlos; Lacroix, Bertrand; Lara Muñoz, Patricia; Conejero, Salvador (Royal Society of Chemistry, 2020)N-Heterocyclic Thiones (NHT) proved to be efficient ligands for the stabilization of small platinum nanoparticles (1.3-1.7 ...
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Reversible carbon-boron bond formation at platinum centers through σ-BH complexes
Ríos Moreno, Pablo; Martín de la Calle, Rocío; Vidossich, Pietro; Fernández de Córdova Martín, Francisco José; Lledós, Agustí; Conejero, Salvador (Royal Society of Chemistry, 2021)A reversible carbon–boron bond formation has been observed in the reaction of the coordinatively unsaturated, cyclometalated, ...