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Listar por autor "Campos, Jesús"
Mostrando ítems 1-20 de 26
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Artículo
A dicoordinate gold(i)–ethylene complex
Navarro, Miquel; Miranda Pizarro, Juan; Moreno Díaz, Juan José; Navarro Gilabert, Carlos; Fernández, Israel; Campos, Jesús (Royal Society of Chemistry, 2021)The use of the exceptionally bulky tris-2-(4,40 -di-tert-butylbiphenylyl) phosphine ligand allows the isolation and ...
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Artículo
A full set of iridium(IV) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties
Shopov, Dimitar Y.; Rudshteyn, Benjamin; Campos, Jesús; Vinyard, David J.; Batista, Victor S.; Brudvig, Gary W.; Crabtree, Robert H. (Royal Society of Chemistry, 2017)We introduce and characterize the complete set of possible isomers of IrIV(pyalk)2Cl2 (pyalk ¼ 2-(pyridin-2-yl)propan-2-oate), ...
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A Genuine Germylene PGeP Pincer Ligand for Formic Acid Dehydrogenation with Iridium
Fernández Buenestado, Marta; Somerville, Rosie J.; López Serrano, Joaquín; Campos, Jesús (Royal Society of Chemistry, 2023)We report an iridium system constructed around a long-tethered PGeP ligand that facilitates access to the less common ...
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Artículo
An Unsaturated Four-Coordinate Dimethyl Dimolybdenum Complex with a Molybdenum–Molybdenum Quadruple Bond
Curado, Natalia; Carrasco, Mario; Campos, Jesús; Maya Díaz, Celia María; Rodríguez, Amor; Ruiz, E.; Álvarez, Santiago; Carmona Guzmán, Ernesto (John Wiley & Sons, 2017)We describe the synthesis and the molecular and electronic structures of the complex [Mo2Me2{μ‐HC(NDipp)2}2] (2; ...
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Artículo
Cooperative activation of X–H (X = H, C, O, N) bonds by a Pt(0)/Ag(i) metal-only Lewis pair
Hidalgo, Nereida; Maya Díaz, Celia María; Campos, Jesús (Royal Society of Chemistry, 2019)Metal-only Lewis pairs made of Pt(0)/Ag(I) combinations have been previously reported, but their cooperative reactivity ...
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Artículo
Dehydrogenative Double C−H Bond Activation in a Germylene-Rhodium Complex
Bajo Velázquez, Sonia; Alcaide, María M.; López Serrano, Joaquín; Campos, Jesús (Wiley, 2021)Transition metal tetrylene complexes offer great opportunities for molecular cooperation due to the ambiphilic character ...
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Artículo
Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition Metal Only Frustrated Lewis Pair
Campos, Jesús (American Chemical Society, 2017)The first example of a Frustrated Lewis Pair (FLP) solely constructed around transition metal centers is described in this ...
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Artículo
Enhanced Dihydrogen Activation by Mononuclear Iridium(II) Compounds: A Mechanistic Study
Hidalgo, Nereida; Moreno Díaz, Juan José; García Rubio, Inés; Campos, Jesús (Wiley, 2022)The organometallic chemistry of 4d and 5d transition metals has been vastly dominated by closed-shell states. The reactivity ...
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Ligand Postsynthetic Functionalization with Fluorinated Boranes and Implications in Hydrogenation Catalysis
G. Alférez, Macarena; Moreno Díaz, Juan José; Gaona, Miguel A.; Maya Díaz, Celia María; Campos, Jesús (American Chemical Society, 2023)The incorporation of boron functionalities into transition-metal catalysts has become a promising strategy to improve ...
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Artículo
Ligand Rearrangement and Hemilability in R hodium(I) and Iridium(I) Complexes Bearing Terphenyl Phosphines
Moreno Díaz, Juan José; Fernández Espada, María; Krüger, Eric; López Serrano, Joaquín; Campos, Jesús; Carmona Guzmán, Ernesto (Wiley, 2018)We describe the synthesis of a series of cationic rhodium(I) and iridium(I) compounds stabilized by ...
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Mechanism of Dihydrogen Splitting by An Apparent Bimetallic Frustrated Lewis Pair based on Ir(III)/Pt(0)
Moreno Díaz, Juan José; Pita Milleiro, Alejandra; Luque Gómez, Ana; Espada, María F.; López Serrano, Joaquín; Campos, Jesús (Wiley-Blackwell, 2023)The incorporation of transition metals into frustrated Lewis pairs (FLPs) offers multiple opportunities for bond activation ...
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Artículo
Metal-only Lewis Pairs of Rhodium with s, p and d-Block Metals
Bajo Velázquez, Sonia; González Alférez, Macarena; Moreno Alcaide, María; López Serrano, Joaquín; Campos, Jesús (Wiley, 2020)Metal-only Lewis pairs (MOLPs) in which the two metal fragments are solely connected by a dative M→M bond represent ...
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Artículo
Methyl Complexes of the Transition Metals
Campos, Jesús; López Serrano, Joaquín; Peloso, Riccardo; Carmona Guzmán, Ernesto (John Wiley & Sons, 2016)Organometallic chemistry can be considered as a wide area of knowledge that combines concepts of classic organic chemistry, ...
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Artículo
Polarized Au(i)/Rh(i) Bimetallic Pairs Cooperatively Trigger Ligand Non-innocence and Bond Activation
Alférez, Macarena G.; Moreno Díaz, Juan José; Maya Díaz, Celia María; Campos, Jesús (Royal Society of Chemistry, 2023)The combination of molecular metallic fragments of contrasting Lewis character offers many possibilities for cooperative ...
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Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity
Hidalgo, Nereida; Romero Pérez, Carlos; Maya Díaz, Celia María; Fernández, Israel; Campos, Jesús (American Chemical Society, 2021)Metal-only Lewis pairs (MOLPs) based on zinc electrophiles are particularly interesting due to their relevance to Negishi ...
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Artículo
Reversible Hydride Migration from C5Me5 to RhI Revealed by a Cooperative Bimetallic Approach
Alférez, Macarena G.; Moreno Díaz, Juan José; Hidalgo Reinoso, Nereida; Campos, Jesús (Wiley, 2020)The use of cyclopentadienyl ligands in organome-tallic chemistry and catalysis is ubiquitous, mostly due to theirrobust ...
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Artículo
Rhodium and Iridium Complexes of Bulky Tertiary Phosphine Ligands. Searching for Isolable Cationic M(III) Alkylidenes
Campos, Jesús; Carmona Guzmán, Ernesto (American Chemical Society, 2015)Cyclometalated chloride complexes of rhodium and iridium based on (5-C5Me5)M(III) fragments that result from the metalation ...
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Tesis Doctoral
Síntesis y aplicaciones catalíticas de complejos de Rh e Ir con ligandos fosfina y ciclopentadienilo
Campos, Jesús (2012-11-09)La Química Organometálica se ha desarrollado de forma extraordinaria desde sus comienzos a mediados del siglo XX, como se ...
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Artículo
Small molecule activation with bimetallic systems: a landscape of cooperative reactivity
Navarro, Miquel; Moreno Díaz, Juan José; Pérez Jiménez, Marina; Campos, Jesús (Royal Society of Chemistry, 2022-09-06)There is growing interest in the design of bimetallic cooperative complexes, which have emerged due to their potential for ...
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Artículo
Structural Snapshots of π-Arene Bonding in a Gold Germylene Cation
Bajo Velázquez, Sonia; Alcaide, María M.; López Serrano, Joaquín; Campos, Jesús (Wiley, 2020)Heavier group 14 element cations exhibit a remarkable reactivity that has typically hampered their isolation. For the few ...