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Listar por autor "Álvarez González, Eleuterio"
Mostrando ítems 21-40 de 76
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Artículo
Evaluating stereoelectronic properties of bulky dialkylterphenyl phosphine ligands
Marín Gómez, Mario; Moreno Díaz, Juan José; Alcaide, María M.; Álvarez González, Eleuterio; López Serrano, Joaquín; Campos Manzano, Jesús; Nicasio Jaramillo, María del Carmen; Carmona Guzmán, Ernesto (Elsevier, 2019)The stereoelectronic properties of a series of sterically hindered phosphines containing a terphenyl substituent, PR2Ar’ ...
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Experimental and Computational Studies of the Molybdenum-Flanking Arene Interaction in Quadruply Bonded Dimolybdenum Complexes with Terphenyl Ligands
Carrasco, Mario; Mendoza, Irene; Álvarez González, Eleuterio; Grirrane, Abdessamad; Maya Díaz, Celia María; Peloso, Riccardo; Rodríguez, Amor; Falceto, Andrés; Álvarez, Santiago; Carmona Durán, Ernesto (Wiley, 2015)To clarify the nature of the Mo[BOND]Carene interaction in terphenyl complexes with quadruple Mo[BOND]Mo bonds, ether ...
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Facile Oxygen Atom Insertion into Unactivated C(sp3)-C(sp2) Single Bonds in Reactions of Iridium(III) Complexes with O2
Cristóbal Gasga, Crispín Silvano; Álvarez González, Eleuterio; Paneque Sosa, Margarita; López Poveda, Manuel (American Chemical Society, 2013)The Ir(III) pyridylidene TpMe2tiebar above startr(CH2CH2-o-tiebar above endC6H4)(tiebar above startCN(H)CHCHCHtiebar above ...
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Formation of β-Metallanaphthalenes by the Coupling of a Benzo-Iridacyclopentadiene with Olefins
Vivancos Ureña, Ángela; Hernández, Yohar A.; Paneque Sosa, Margarita; López Poveda, Manuel; Salazar Pereda, Verónica; Álvarez González, Eleuterio (American Chemical Society, 2015)We have synthesized a new type of metallaaromatic complexes, namely the hydride-β-iridanaphthalenes TpMe2tiebar above ...
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Functionalization of 3-Iridacyclopentenes
Gómez González, Margarita; Rendón Márquez, Nuria; Álvarez González, Eleuterio; Mereiter, Kurt; López Poveda, Manuel; Paneque Sosa, Margarita; Wolffrearrangement (Wiley, 2017)Members of a series of iridacyclopentenes of composition [TpMe2Ir(k2-C,C-CH2CR′=CRCH2)(CO)] (TpMe2=hydrotris(3,5-dimethylpyrazolyl)borate; ...
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Artículo
Halide encapsulation by dicarboxylate oxido-vanadium cage complexes
Gómez, Margarita; Pastor Navarro, Antonio; Álvarez González, Eleuterio; Olloqui Sariego, José Luis; Galindo del Pozo, Agustín (The Royal Society of Chemistry, 2018)Compounds [Bu4N]2[V8O16(oda)4⊂2Cl], 1, [Bu4N]2[V8O16(glut)4⊂2Cl], 2, and [Bu4N][V4O8(glut)2⊂F], 3, (oda = oxydiacetate, ...
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Artículo
Highly enantioselective imine hydrogenation catalyzed by ruthenium phosphane-phosphite diamine complexes
Vaquero Gutiérrez, Mónica; Suárez Escobar, Andrés Luis; Vargas Rodríguez, Sergio; Bottari, Giovanni; Álvarez González, Eleuterio; Pizzano Mancera, Antonio (John Wiley & Sons, 2012)Mildly does it: A highly enantioselective catalyst for the hydrogenation of N-aryl imines is described (see scheme). This ...
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Homochiral imidazolium-based dicarboxylate silver(i) compounds: synthesis, characterisation and antimicrobial properties
Carrasco Carrasco, Carlos Jesús; Montilla Ramos, Francisco Javier; Álvarez González, Eleuterio; Galindo del Pozo, Agustín; Pérez Aranda, María; Pajuelo Domínguez, Eloísa; Alcudia Cruz, Ana (Royal Society of Chemistry, 2022-03)Complexes [Ag(LR)], 2 (LR = 2,2′-(imidazolium-1,3-diyl)di(2-alkylacetate)), were prepared by treatment of compounds HLR, ...
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Hydroboration of carbon dioxide with catechol- and pinacolborane using an Ir–CNP* pincer complex. Water influence on the catalytic activity
Sánchez Mellado, Práxedes; Hernández Juárez, Martín; Rendón Márquez, Nuria; López Serrano, Joaquín; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2018)Iridium complexes based on deprotonated lutidine-derived CNP* pincers 2a/2b selectively catalyzed the hydroboration of ...
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Hydrogenation of an iridium-coordinated imidazol-2-ylidene ligand fragment
Hernández Juárez, Martín; López Serrano, Joaquín; González Herrero, P.; Rendón Márquez, Nuria; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2018)An iridium complex featuring a metalated lutidine-derived CNP ligand reacts with KOt Bu to yield a dimeric species with ...
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Hydrogenation of imines catalysed by ruthenium(ii) complexes based on lutidine-derived CNC pincer ligands
Hernández Juárez, Martín; Vaquero Gutiérrez, Mónica; Álvarez González, Eleuterio; Salazar Pereda, Verónica; Suárez Escobar, Andrés Luis (Royal Society of Chemistry (Great Britain), 2013)The preparation of new Ru(ii) complexes incorporating fac-coordinated lutidine-derived CNC ligands is reported. These ...
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Hydrogenation/dehydrogenation of N-heterocycles catalyzed by ruthenium complexes based on multimodal proton-responsive CNN(H) pincer ligands
Sánchez Mellado, Práxedes; Hernández Juárez, Martín; Rendón Márquez, Nuria; López Serrano, Joaquín; López Santos, Laura; Álvarez González, Eleuterio; Paneque Sosa, Margarita; Suárez Escobar, Andrés Luis (Royal Society of Chemistry, 2020)Ru complexes based on lutidine-derived pincer CNN(H) ligands having secondary amine side donors are efficient precatalysts ...
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Influence of N-donor bases and the solvent in oxodiperoxomolybdenum catalysed olefin epoxidation with hydrogen peroxide in ionic liquids
Herbert, Matthew; Montilla Ramos, Francisco Javier; Galindo del Pozo, Agustín; Moyano López, Raquel; Pastor Navarro, Antonio; Álvarez González, Eleuterio (Royal Society of Chemistry, 2011)Biphasic catalytic olefin epoxidation systems consisting of oxodiperoxomolybdenum catalysts in 1- n -alkyl-3-methylimidazolium ...
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Investigations on the Coupling of Ethylene and Alkynes in Tp Me2 Ir Compounds: Water as an Effective Trapping Agent
Álvarez González, Eleuterio; Paneque Sosa, Margarita; Martín Posadas, Cristina Isabel; López Poveda, Manuel; Rendón Márquez, Nuria; Mereiter, Kurt (Wiley-VCH, 2007)The reaction of the bis(ethylene) complex [TpMe2Ir(C2H4)2] (1) (TpMe: hydrotris(3,5-dimethylpyrazolyl)borate) with two ...
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Isolation and X-ray characterization of palladium-N complexes in the guanylation of aromatic amines. Mechanistic implications
García, Hermenegildo; Álvarez González, Eleuterio; Grirrane, Abdessamad (2013)In the context of palladium-catalyzed guanylation of anilines herein, we have been able to characterize and isolate ...
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Lithium Di-‐ and Trimethyl Dimolybdenum(II) Complexes with Mo-‐Mo Quadruple Bonds and Bridging Methyl Groups
Curado, Natalia; Carrasco, Mario; Álvarez González, Eleuterio; Maya Díaz, Celia María; Peloso, Riccardo; Rodríguez, Amor; López Serrano, Joaquín; Carmona Guzmán, Ernesto (American Chemical Society, 2015)New dimolybdenum complexes of composition [Mo2{μ-Me}2Li(S)}(μ- X)(μ-N^N)2] (3a−3c), where S = THF or Et2O and N^N represents ...
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Mechanism of Alkyl Migration in Diorganomagnesium 2,6-Bis(imino)pyridine Complexes: Formation of Grignard-Type Complexes with Square-Planar Mg(II) Centers
Sandoval, John J.; Palma, Pilar; Álvarez González, Eleuterio; Cámpora Pérez, Juan; Rodríguez Delgado, Antonio (American Chemical Society, 2016)Dialkylmagnesium compounds [MgR2L2] (R = n-Bu, L = none or R = Bn, L = THF) react with 2,6-bis(imino)pyridines (BIP) to ...
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Artículo
Migratory insertion reactions of nickel and palladium σ-alkyl complexes with a phosphinito-imine ligand†‡
Ortíz de la Tabla González, Laura; Matas Ruíz, Inmaculada; Álvarez González, Eleuterio; Cámpora Pérez, Juan (Royal Society of Chemistry (Great Britain), 2012)Ligand exchange reactions have been used for the synthesis of metallacyclic complexes of Ni and Pd of the type [M[upper ...
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N-substituted Aminobiphenyl Palladacycles Stabilized by Dialkylterphenyl Phosphanes: Preparation and Applications in C[sbnd]N Cross-coupling Reactions
Monti, Andrea; Jiménez Rama, Raquel; Gómez, Beatriz; Maya Díaz, Celia María; Álvarez González, Eleuterio; Carmona Guzmán, Ernesto; Nicasio Jaramillo, María del Carmen (Elsevier, 2021)Neutral and cationic N-methyl- and N-phenyl-2-aminobiphenyl methanesulfonate palladacycles stabilized with dialkylterphenyl ...
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{[Na1(µ-H2O)Na2]2[(C2O4)2Cr(µ-OH)2-Cr(C2O4)2]·H2O}n, a novel hydrated form
Bélombé, Michel M.; Nenwa, Justin; Ngouné, Jean; Álvarez González, Eleuterio; Galindo del Pozo, Agustín (2010)